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Tabatabaee M, Aghabozorg H, Nasrolahzadeh R, et al. Butane-1,4-diammonium bis-(pyridine-2,6-dicarboxyl-ato-κO,N,O)cadmate(II) dihydrate. Acta Crystallogr Sect E Struct Rep Online. 2008;64:m1290doi: 10.1107/S1600536808029395.
Tabatabaee, M., Aghabozorg, H., Nasrolahzadeh, R., Roshan, L., & Firoozi, N. (2008). Butane-1,4-diammonium bis-(pyridine-2,6-dicarboxyl-ato-κO,N,O)cadmate(II) dihydrate. Acta crystallographica. Section E, Structure reports online, 64m1290. https://doi.org/10.1107/S1600536808029395
Tabatabaee, Masoumeh, et al. "Butane-1,4-diammonium bis-(pyridine-2,6-dicarboxyl-ato-κO,N,O)cadmate(II) dihydrate." Acta crystallographica. Section E, Structure reports online vol. 64 (2008): m1290. doi: https://doi.org/10.1107/S1600536808029395
Tabatabaee M, Aghabozorg H, Nasrolahzadeh R, Roshan L, Firoozi N. Butane-1,4-diammonium bis-(pyridine-2,6-dicarboxyl-ato-κO,N,O)cadmate(II) dihydrate. Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 20;64:m1290. doi: 10.1107/S1600536808029395. PMID: 21201034; PMCID: PMC2959406.
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Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 20;64:m1290. doi: 10.1107/S1600536808029395.

Butane-1,4-diammonium bis-(pyridine-2,6-dicarboxyl-ato-κO,N,O)cadmate(II) dihydrate.

Acta crystallographica. Section E, Structure reports online

Masoumeh Tabatabaee, Hossein Aghabozorg, Roghaieh Nasrolahzadeh, Leila Roshan, Najmeh Firoozi

PMID: 21201034 PMCID: PMC2959406 DOI: 10.1107/S1600536808029395

Abstract

In the title compound, (C(4)H(14)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O, the Cd(II) ion is coordinated by four O atoms [Cd-O = 2.2399 (17)-2.2493 (17) Å] and two N atoms [Cd-N = 2.3113 (15) and 2.3917 (15) Å] from two tridentate pyridine-2,6-dicarboxyl-ato ligands in a distorted octa-hedral geometry. The uncoordinated water mol-ecules are involved in O-H⋯O and N-H⋯O hydrogen bonds, which contribute to the formation of a three-dimensional supra-molecular structure, along with π-π stacking inter-actions [centroid-centroid distances of 3.5313 (13) and 3.6028 (11) Å between the pyridine rings of neighbouring dianions].

References

  1. Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22 - PubMed
  2. Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 30;64(Pt 5):m743-4 - PubMed

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