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Eltayeb NE, Teoh SG, Chantrapromma S, et al. Chlorido{5,5'-dimethyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III). Acta Crystallogr Sect E Struct Rep Online. 2008;64:m570-1doi: 10.1107/S1600536808007459.
Eltayeb, N. E., Teoh, S. G., Chantrapromma, S., Fun, H. K., & Adnan, R. (2008). Chlorido{5,5'-dimethyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III). Acta crystallographica. Section E, Structure reports online, 64m570-1. https://doi.org/10.1107/S1600536808007459
Eltayeb, Naser Eltaher, et al. "Chlorido{5,5'-dimethyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III)." Acta crystallographica. Section E, Structure reports online vol. 64 (2008): m570-1. doi: https://doi.org/10.1107/S1600536808007459
Eltayeb NE, Teoh SG, Chantrapromma S, Fun HK, Adnan R. Chlorido{5,5'-dimethyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III). Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 29;64:m570-1. doi: 10.1107/S1600536808007459. PMID: 21202022; PMCID: PMC2960927.
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Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 29;64:m570-1. doi: 10.1107/S1600536808007459.

Chlorido{5,5'-dimethyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III).

Acta crystallographica. Section E, Structure reports online

Naser Eltaher Eltayeb, Siang Guan Teoh, Suchada Chantrapromma, Hoong-Kun Fun, Rohana Adnan

PMID: 21202022 PMCID: PMC2960927 DOI: 10.1107/S1600536808007459

Abstract

In the title complex, [Mn(C(22)H(18)N(2)O(2))Cl], the Mn(III) center is in a distorted square-pyramidal configuration; the basal plane is formed by the N(2)O(2) donors of the tetra-dentate Schiff base dianion, with the two phenol O atoms and two imine N atoms each mutually cis. The chloride ion occupies the apical coordination site. The dihedral angle between the two outer phenolate rings of the tetra-dentate ligand is 18.24 (9)°. The central benzene ring makes dihedral angles of 13.71 (8) and 30.50 (8)° with the two outer phenolate rings. In the crystal structure, weak C-H⋯Cl inter-actions link the mol-ecules into screw helices along the b direction. These helices are further connected by weak C-H⋯O inter-actions into a three-dimensional network. The crystal structure is further stabilized by C-H⋯π inter-actions involving the central benzene ring.

References

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