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Polishchuk AV, Gerasimenko AV, Gayvoronskaya KA, et al. Tetra-kis(dihydrogen pefloxacinium) di-μ(2)-chlorido-bis-[tetra-chloridobismuthate(III)] tetra-chloride octa-hydrate. Acta Crystallogr Sect E Struct Rep Online. 2008;64:m931-2doi: 10.1107/S1600536808017674.
Polishchuk, A. V., Gerasimenko, A. V., Gayvoronskaya, K. A., & Karaseva, E. T. (2008). Tetra-kis(dihydrogen pefloxacinium) di-μ(2)-chlorido-bis-[tetra-chloridobismuthate(III)] tetra-chloride octa-hydrate. Acta crystallographica. Section E, Structure reports online, 64m931-2. https://doi.org/10.1107/S1600536808017674
Polishchuk, A V, et al. "Tetra-kis(dihydrogen pefloxacinium) di-μ(2)-chlorido-bis-[tetra-chloridobismuthate(III)] tetra-chloride octa-hydrate." Acta crystallographica. Section E, Structure reports online vol. 64 (2008): m931-2. doi: https://doi.org/10.1107/S1600536808017674
Polishchuk AV, Gerasimenko AV, Gayvoronskaya KA, Karaseva ET. Tetra-kis(dihydrogen pefloxacinium) di-μ(2)-chlorido-bis-[tetra-chloridobismuthate(III)] tetra-chloride octa-hydrate. Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 19;64:m931-2. doi: 10.1107/S1600536808017674. PMID: 21202786; PMCID: PMC2961801.
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Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 19;64:m931-2. doi: 10.1107/S1600536808017674.

Tetra-kis(dihydrogen pefloxacinium) di-μ(2)-chlorido-bis-[tetra-chloridobismuthate(III)] tetra-chloride octa-hydrate.

Acta crystallographica. Section E, Structure reports online

A V Polishchuk, A V Gerasimenko, K A Gayvoronskaya, E T Karaseva

Affiliations

  1. Institute of Chemistry, FEB RAS, Prospekt 100-letiya Vladivostoka 159, Vladivostok 690022, Russian Federation.

PMID: 21202786 PMCID: PMC2961801 DOI: 10.1107/S1600536808017674

Abstract

The title compound {systematic name: tetra-kis[4-(3-carb-oxy-1-ethyl-6-fluoro-4-hydroxonio-1,4-dihydro-7-quinol-yl)-1-meth-yl-piperazin-1-ium] di-μ(2)-chlorido-bis-[tetra-chlorido-bismuth-ate(III)] tetra-chloride octa-hydrate}, (C(17)H(22)FN(3)O(3))(4)[Bi(2)Cl(10)]Cl(4)·8H(2)O, is composed of edge-shared centrosymmetric dinuclear [Bi(2)Cl(10)](4-) anions, Cl(-) anions, dihydrogen pefloxacinium cations and water mol-ecules. The Bi(III) coordination polyhedron is a distorted octa-hedron. There are four short terminal Bi-Cl bonds [2.5037 (10)-2.6911 (7) Å] and two longer bridging bonds [2.8834 (8) and 3.0687 (9) Å] in each octa-hedron. Two sets of chloride ions and water mol-ecules are disordered over the same sites with site occupancies of 1/3 and 2/3, respectively. Anions, cations and water mol-ecules are linked by O-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds, forming a three-dimensional framework. There are also π-π stacking inter-actions between quinoline ring systems [centroid-centroid distance = 3.575 (1) Å].

References

  1. Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):380-8 - PubMed
  2. Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22 - PubMed

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