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Telalović S, Ramanathan A, Ng JF, et al. On the synergistic catalytic properties of bimetallic mesoporous materials containing aluminum and zirconium: the Prins cyclisation of citronellal. Chemistry. 2011;17(7):2077-88doi: 10.1002/chem.201002909.
Telalović, S., Ramanathan, A., Ng, J. F., Maheswari, R., Kwakernaak, C., Soulimani, F., Brouwer, H. C., Chuah, G. K., Weckhuysen, B. M., & Hanefeld, U. (2011). On the synergistic catalytic properties of bimetallic mesoporous materials containing aluminum and zirconium: the Prins cyclisation of citronellal. Chemistry (Weinheim an der Bergstrasse, Germany), 17(7), 2077-88. https://doi.org/10.1002/chem.201002909
Telalović, Selvedin, et al. "On the synergistic catalytic properties of bimetallic mesoporous materials containing aluminum and zirconium: the Prins cyclisation of citronellal." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 17,7 (2011): 2077-88. doi: https://doi.org/10.1002/chem.201002909
Telalović S, Ramanathan A, Ng JF, Maheswari R, Kwakernaak C, Soulimani F, Brouwer HC, Chuah GK, Weckhuysen BM, Hanefeld U. On the synergistic catalytic properties of bimetallic mesoporous materials containing aluminum and zirconium: the Prins cyclisation of citronellal. Chemistry. 2011 Feb 11;17(7):2077-88. doi: 10.1002/chem.201002909. Epub 2011 Jan 21. PMID: 21259348; PMCID: PMC3072521.
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Chemistry. 2011 Feb 11;17(7):2077-88. doi: 10.1002/chem.201002909. Epub 2011 Jan 21.

On the synergistic catalytic properties of bimetallic mesoporous materials containing aluminum and zirconium: the Prins cyclisation of citronellal.

Chemistry (Weinheim an der Bergstrasse, Germany)

Selvedin Telalović, Anand Ramanathan, Jeck Fei Ng, Rajamanickam Maheswari, Cees Kwakernaak, Fouad Soulimani, Hans C Brouwer, Gaik Khuan Chuah, Bert M Weckhuysen, Ulf Hanefeld

Affiliations

  1. Gebouw voor Scheikunde, Technische Universiteit Delft, Julianalaan 136, 2628 BL Delft, The Netherlands.

PMID: 21259348 PMCID: PMC3072521 DOI: 10.1002/chem.201002909

Abstract

Bimetallic three-dimensional amorphous mesoporous materials, Al-Zr-TUD-1 materials, were synthesised by using a surfactant-free, one-pot procedure employing triethanolamine (TEA) as a complexing reagent. The amount of aluminium and zirconium was varied in order to study the effect of these metals on the Brønsted and Lewis acidity, as well as on the resulting catalytic activity of the material. The materials were characterised by various techniques, including elemental analysis, X-ray diffraction, high-resolution TEM, N(2) physisorption, temperature-programmed desorption (TPD) of NH(3), and (27) Al MAS NMR, XPS and FT-IR spectroscopy using pyridine and CO as probe molecules. Al-Zr-TUD-1 materials are mesoporous with surface areas ranging from 700-900 m(2) g(-1), an average pore size of around 4 nm and a pore volume of around 0.70 cm(3) g(-1). The synthesised Al-Zr-TUD-1 materials were tested as catalyst materials in the Lewis acid catalysed Meerwein-Ponndorf-Verley reduction of 4-tert-butylcyclohexanone, the intermolecular Prins synthesis of nopol and in the intramolecular Prins cyclisation of citronellal. Although Al-Zr-TUD-1 catalysts possess a lower amount of acid sites than their monometallic counterparts, according to TPD of NH(3), these materials outperformed those of the monometallic Al-TUD-1 as well as Zr-TUD-1 in the Prins cyclisation of citronellal. This proves the existence of synergistic properties of Al-Zr-TUD-1. Due to the intramolecular nature of the Prins cyclisation of citronellal, the hydrophilic surface of the catalyst as well as the presence of both Brønsted and Lewis acid sites synergy could be obtained with bimetallic Al-Zr-TUD-1. Besides spectroscopic investigation of the active sites of the catalyst material a thorough testing of the catalyst in different types of reactions is crucial in identifying its specific active sites.

Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

References

  1. Chemistry. 2001 Apr 1;7(7):1437-43 - PubMed
  2. Chem Commun (Camb). 2009 Jan 28;(4):460-2 - PubMed
  3. Chem Commun (Camb). 2008 Oct 14;(38):4631-3 - PubMed
  4. New J Chem. 2010 Jan 12;20(4):642-658 - PubMed
  5. Chem Commun (Camb). 2010 May 28;46(20):3466-8 - PubMed
  6. J Org Chem. 2007 Nov 23;72(24):9121-33 - PubMed
  7. Chemistry. 2008;14(3):961-72 - PubMed
  8. J Org Chem. 2007 Nov 23;72(24):9376-8 - PubMed
  9. Chemistry. 2004 Apr 19;10(8):2088-93 - PubMed
  10. Org Biomol Chem. 2010 Jun 21;8(12):2845-9 - PubMed
  11. Chem Commun (Camb). 2010 Nov 7;46(41):7825-7 - PubMed
  12. J Am Chem Soc. 2007 Sep 12;129(36):11161-71 - PubMed
  13. Chem Commun (Camb). 2004 Jun 21;(12):1404-5 - PubMed

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