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Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 19;67:m352. doi: 10.1107/S1600536811005563.

(2,2'-Bipyridine-κN,N')bis-(3-meth-oxy-benzoato-κO,O)copper(II) mono-hydrate.

Acta crystallographica. Section E, Structure reports online

Ming-Hao Lin, Jing-Fan Zhou, Bin-Bin Liu, Jian-Li Lin

Affiliations

  1. State Key Laboratory Base of Novel Functional Materials and Preparation Science, Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, Zhejiang, 315211, People's Republic of China.

PMID: 21522281 PMCID: PMC3052164 DOI: 10.1107/S1600536811005563

Abstract

The title compound, [Cu(C(8)H(7)O(3))(2)(C(10)H(8)N(2))]·H(2)O, is comprised of a Cu(II) ion, two 3-meth-oxy-benzoate ligands, a 2,2'-bipyridine (bipy) ligand and one uncoordinated water mol-ecule. The Cu(II) ion and the water O atom lie on a twofold axis. The Cu(II) ion exhibits a six-coordinate distorted octa-hedral geometry, with two N atoms from the bipy ligand [Cu-N = 1.9996 (16) Å] and four O atoms from two 3-meth-oxy-benzoate ligands [Cu-O = 1.9551 (15) and 2.6016 (16) Å]. The mol-ecules are linked by O-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional network.

References

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