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Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 17;66:m937. doi: 10.1107/S1600536810027212.

Bis{μ-4,4',6,6'-tetra-tert-butyl-2,2'-[N-(2-oxidoeth-yl)imino-dimethyl-ene]diphenolato}dialuminium(III).

Acta crystallographica. Section E, Structure reports online

Stephanie L Hemmingson, Alice J Stevens, Joseph M Tanski, Yutan D Y L Getzler

PMID: 21588169 PMCID: PMC3007319 DOI: 10.1107/S1600536810027212

Abstract

The title compound, [Al(2)(C(32)H(48)NO(3))(2)], exists as a dimer with bridging ethoxide groups. It was isolated from a reaction mixture of the parent ligand and trimethyl-aluminium in tetra-hydro-furan. The geometry around the Al(III) atom is a slightly distorted trigonal-bipyramid, typical of atrane derivatives.

References

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