Display options
Cite
Burgoyne AR, Meijboom R, Muller A, et al. trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate. Acta Crystallogr Sect E Struct Rep Online. 2010;66:m1380-1doi: 10.1107/S1600536810039814.
Burgoyne, A. R., Meijboom, R., Muller, A., & Omondi, B. O. (2010). trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate. Acta crystallographica. Section E, Structure reports online, 66m1380-1. https://doi.org/10.1107/S1600536810039814
Burgoyne, Andrew R, et al. "trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate." Acta crystallographica. Section E, Structure reports online vol. 66 (2010): m1380-1. doi: https://doi.org/10.1107/S1600536810039814
Burgoyne AR, Meijboom R, Muller A, Omondi BO. trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate. Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 09;66:m1380-1. doi: 10.1107/S1600536810039814. PMID: 21588819; PMCID: PMC3009219.
Copy Download .nbib Format: NLM
Share it on

Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 09;66:m1380-1. doi: 10.1107/S1600536810039814.

trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate.

Acta crystallographica. Section E, Structure reports online

Andrew R Burgoyne, Reinout Meijboom, Alfred Muller, Bernard O Omondi

Affiliations

  1. Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524 Auckland Park, Johannesburg, 2006, South Africa.

PMID: 21588819 PMCID: PMC3009219 DOI: 10.1107/S1600536810039814

Abstract

The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27 (2)° and Rh-P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl-Rh unit results in a reduced P-Rh-Cl angle of 86.675 (15)°.

References

  1. Acta Crystallogr C. 2001 Jul;57(Pt 7):793-5 - PubMed
  2. Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22 - PubMed

Publication Types