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Kitiphaisalnont P, Siripaisarnpipat S, Chaichit N. Di-μ(4)-succinato-tetra-kis[aqua-phenanthrolinecopper(II)] tetra-nitrate tetra-hydrate. Acta Crystallogr Sect E Struct Rep Online. 2009;65:m1284doi: 10.1107/S1600536809039580.
Kitiphaisalnont, P., Siripaisarnpipat, S., & Chaichit, N. (2009). Di-μ(4)-succinato-tetra-kis[aqua-phenanthrolinecopper(II)] tetra-nitrate tetra-hydrate. Acta crystallographica. Section E, Structure reports online, 65m1284. https://doi.org/10.1107/S1600536809039580
Kitiphaisalnont, Panana, et al. "Di-μ(4)-succinato-tetra-kis[aqua-phenanthrolinecopper(II)] tetra-nitrate tetra-hydrate." Acta crystallographica. Section E, Structure reports online vol. 65 (2009): m1284. doi: https://doi.org/10.1107/S1600536809039580
Kitiphaisalnont P, Siripaisarnpipat S, Chaichit N. Di-μ(4)-succinato-tetra-kis[aqua-phenanthrolinecopper(II)] tetra-nitrate tetra-hydrate. Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 03;65:m1284. doi: 10.1107/S1600536809039580. PMID: 21578054; PMCID: PMC2971199.
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Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 03;65:m1284. doi: 10.1107/S1600536809039580.

Di-μ(4)-succinato-tetra-kis[aqua-phenanthrolinecopper(II)] tetra-nitrate tetra-hydrate.

Acta crystallographica. Section E, Structure reports online

Panana Kitiphaisalnont, Sutatip Siripaisarnpipat, Narongsak Chaichit

PMID: 21578054 PMCID: PMC2971199 DOI: 10.1107/S1600536809039580

Abstract

In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetra-cation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N'-bidentate phenanthroline mol-ecule, two O-monodentate bis-bridging succinate dianions and a water mol-ecule, resulting in distorted CuN(2)O(3) square-based pyramidal geometries for the metal ions, with the water mol-ecule occupying the apical site. In the crystal, the components are linked by O-H⋯O hydrogen bonds and aromatic π-π stacking inter-actions [minimum centroid-centroid separation = 3.537 (2) Å].

References

  1. Inorg Chem. 2007 Apr 16;46(8):3057-71 - PubMed
  2. Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22 - PubMed

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