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Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 10;66:m503-4. doi: 10.1107/S1600536810011724.

Bis(dicyclo-hexyl-phenyl-phosphine)silver(I) nitrate.

Acta crystallographica. Section E, Structure reports online

Andrew R Burgoyne, Reinout Meijboom, Alfred Muller, Bernard Omondi

Affiliations

  1. Synthesis and Catalysis Research Centre, Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park, Johannesburg, South Africa 2006.

PMID: 21579003 PMCID: PMC2979226 DOI: 10.1107/S1600536810011724

Abstract

The title compound, [Ag(C(18)H(27)P)(2)]NO(3), is a mononuclear salt species in which the Ag atom is coordinated by two phosphine ligands, forming a cation, with the nitrate as the counter-anion, weakly inter-acting with the Ag atom, resulting in Ag⋯O distances of 2.602 (6) and 2.679 (6) Å. The cationic silver-phosphine complex has a non-linear geometry in which the P-Ag-P angle is 154.662 (19)°. The Ag-P bond lengths are 2.4303 (6) and 2.4046 (5) Å.

References

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