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Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 13;65:o517. doi: 10.1107/S1600536809004632.

(S(P),S(P))-(-)-(E)-1,2-Bis(methyl-phenyl-phosphino-yl)ethene.

Acta crystallographica. Section E, Structure reports online

Holger Butenschön, Nikolai Vinokurov, Ingmar Baumgardt, K Michal Pietrusiewicz

PMID: 21582180 PMCID: PMC2968589 DOI: 10.1107/S1600536809004632

Abstract

The title compound, C(16)H(18)O(2)P(2), possesses two stereogenic P atoms and shows a distorted s-cis conformation of each O=P-C=C moiety. This has been suggested on the basis of the stereochemical result of 1,3-dipolar cyclo-additions with nitro-nes and is now confirmed by the present crystal structure analysis. There are two crystallographically independent molecules in the asymmetric unit.

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