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Meiners J, Scheibel MG, Lemée-Cailleau MH, et al. Square-planar iridium(II) and iridium(III) amido complexes stabilized by a PNP pincer ligand. Angew Chem Int Ed Engl. 2011;50(35):8184-7doi: 10.1002/anie.201102795.
Meiners, J., Scheibel, M. G., Lemée-Cailleau, M. H., Mason, S. A., Boeddinghaus, M. B., Fässler, T. F., Herdtweck, E., Khusniyarov, M. M., & Schneider, S. (2011). Square-planar iridium(II) and iridium(III) amido complexes stabilized by a PNP pincer ligand. Angewandte Chemie (International ed. in English), 50(35), 8184-7. https://doi.org/10.1002/anie.201102795
Meiners, Jenni, et al. "Square-planar iridium(II) and iridium(III) amido complexes stabilized by a PNP pincer ligand." Angewandte Chemie (International ed. in English) vol. 50,35 (2011): 8184-7. doi: https://doi.org/10.1002/anie.201102795
Meiners J, Scheibel MG, Lemée-Cailleau MH, Mason SA, Boeddinghaus MB, Fässler TF, Herdtweck E, Khusniyarov MM, Schneider S. Square-planar iridium(II) and iridium(III) amido complexes stabilized by a PNP pincer ligand. Angew Chem Int Ed Engl. 2011 Aug 22;50(35):8184-7. doi: 10.1002/anie.201102795. Epub 2011 Jul 08. PMID: 21744449.
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Angew Chem Int Ed Engl. 2011 Aug 22;50(35):8184-7. doi: 10.1002/anie.201102795. Epub 2011 Jul 08.

Square-planar iridium(II) and iridium(III) amido complexes stabilized by a PNP pincer ligand.

Angewandte Chemie (International ed. in English)

Jenni Meiners, Markus G Scheibel, Marie-Hélène Lemée-Cailleau, Sax A Mason, M Bele Boeddinghaus, Thomas F Fässler, Eberhardt Herdtweck, Marat M Khusniyarov, Sven Schneider

Affiliations

  1. Department Chemie und Pharmazie, Friedrich-Alexander-Universität, Erlangen, Germany.

PMID: 21744449 DOI: 10.1002/anie.201102795

Abstract

Squaring the circle: the novel dienamido pincer ligand N(CHCHPtBu(2))(2)(-) affords the isolation of the unusual square-planar iridium(II) and iridium(III) amido complexes [IrCl{N(CHCHPtBu(2))(2)}](n) (n=0 (1), +1 (2)). In contrast, the corresponding iridium(I) complex of the redox series (n=-1) is surprisingly unstable. The diamagnetism of 2 is attributed to strong N→Ir π donation.

Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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