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Gladysz JA, Jurisch M. Structural, physical, and chemical properties of fluorous compounds. Top Curr Chem. 2012;308:1-23doi: 10.1007/128_2011_282.
Gladysz, J. A., & Jurisch, M. (2012). Structural, physical, and chemical properties of fluorous compounds. Topics in current chemistry, 3081-23. https://doi.org/10.1007/128_2011_282
Gladysz, John A, and Jurisch, Markus. "Structural, physical, and chemical properties of fluorous compounds." Topics in current chemistry vol. 308 (2012): 1-23. doi: https://doi.org/10.1007/128_2011_282
Gladysz JA, Jurisch M. Structural, physical, and chemical properties of fluorous compounds. Top Curr Chem. 2012;308:1-23. doi: 10.1007/128_2011_282. PMID: 21972027.
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Top Curr Chem. 2012;308:1-23. doi: 10.1007/128_2011_282.

Structural, physical, and chemical properties of fluorous compounds.

Topics in current chemistry

John A Gladysz, Markus Jurisch

Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, TX 77842-3012, USA. [email protected]

PMID: 21972027 DOI: 10.1007/128_2011_282

Abstract

The sizes and structures of fluorous molecules are analyzed, particularly with respect to the helical conformations of perfluoroalkyl segments and their phase separation in crystal lattices. Basic molecular properties, bond energies, and special bonding motifs are reviewed. Solubility, adsorption, and related phenomena are treated. Miscibilities of fluorous solvents, and partition coefficients of solutes in fluorous/organic biphase mixtures, are analyzed. Electronic effects and NMR properties are discussed, and some reactions involving the fluorinated parts of fluorous substances are presented.

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