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Barman S, Furukawa H, Blacque O, et al. Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes. Chem Commun (Camb). 2011;47(43):11882-4doi: 10.1039/c1cc14387e.
Barman, S., Furukawa, H., Blacque, O., Venkatesan, K., Yaghi, O. M., Jin, G. X., & Berke, H. (2011). Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes. Chemical communications (Cambridge, England), 47(43), 11882-4. https://doi.org/10.1039/c1cc14387e
Barman, Samir, et al. "Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes." Chemical communications (Cambridge, England) vol. 47,43 (2011): 11882-4. doi: https://doi.org/10.1039/c1cc14387e
Barman S, Furukawa H, Blacque O, Venkatesan K, Yaghi OM, Jin GX, Berke H. Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes. Chem Commun (Camb). 2011 Nov 21;47(43):11882-4. doi: 10.1039/c1cc14387e. Epub 2011 Oct 10. PMID: 21983899.
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Chem Commun (Camb). 2011 Nov 21;47(43):11882-4. doi: 10.1039/c1cc14387e. Epub 2011 Oct 10.

Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes.

Chemical communications (Cambridge, England)

Samir Barman, Hiroyasu Furukawa, Olivier Blacque, Koushik Venkatesan, Omar M Yaghi, Guo-Xin Jin, Heinz Berke

Affiliations

  1. Department of Inorganic Chemistry, University of Zürich, Winterthurerstrasse 190, CH-8057, Zürich, Switzerland.

PMID: 21983899 DOI: 10.1039/c1cc14387e

Abstract

Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metal-linker complex as a precursor to construct MOF-648.

This journal is © The Royal Society of Chemistry 2011

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