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Seredyuk M, Znovjyak KO, Haukka M, et al. (Tris{2-[(5-hy-droxy-pyridin-2-yl-κN)methyl-idene-imino-κN]eth-yl}amine)-zinc dinitrate. Acta Crystallogr Sect E Struct Rep Online. 2011;67:m1791-2doi: 10.1107/S1600536811048094.
Seredyuk, M., Znovjyak, K. O., Haukka, M., Pavlenko, V. A., & Bokach, N. A. (2011). (Tris{2-[(5-hy-droxy-pyridin-2-yl-κN)methyl-idene-imino-κN]eth-yl}amine)-zinc dinitrate. Acta crystallographica. Section E, Structure reports online, 67m1791-2. https://doi.org/10.1107/S1600536811048094
Seredyuk, Maksym, et al. "(Tris{2-[(5-hy-droxy-pyridin-2-yl-κN)methyl-idene-imino-κN]eth-yl}amine)-zinc dinitrate." Acta crystallographica. Section E, Structure reports online vol. 67 (2011): m1791-2. doi: https://doi.org/10.1107/S1600536811048094
Seredyuk M, Znovjyak KO, Haukka M, Pavlenko VA, Bokach NA. (Tris{2-[(5-hy-droxy-pyridin-2-yl-κN)methyl-idene-imino-κN]eth-yl}amine)-zinc dinitrate. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 01;67:m1791-2. doi: 10.1107/S1600536811048094. Epub 2011 Nov 19. PMID: 22199579; PMCID: PMC3238702.
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Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 01;67:m1791-2. doi: 10.1107/S1600536811048094. Epub 2011 Nov 19.

(Tris{2-[(5-hy-droxy-pyridin-2-yl-κN)methyl-idene-imino-κN]eth-yl}amine)-zinc dinitrate.

Acta crystallographica. Section E, Structure reports online

Maksym Seredyuk, Kateryna O Znovjyak, Matti Haukka, Vadim A Pavlenko, Nadezhda A Bokach

PMID: 22199579 PMCID: PMC3238702 DOI: 10.1107/S1600536811048094

Abstract

In the complex cation of the title compound, [Zn(C(24)H(27)N(7)O(3))](NO(3))(2), the tripodal tris-{[2-(5-hy-droxy-pyridin-2-yl)methyl-idene-imino]-eth-yl}amine ligand is coordin-ated to the Zn atom through the three pyridine and three imino N atoms. The coordination sphere of the Zn atom is based on an octahedron with a significant distortion towards trigonal prismatic, the twist angle being 45.58 (9)°. The crystal packing is formed by L and D anti-podes arranged in layers disposed parallel to the b axis. Strong O-H⋯O hydrogen bonding exists between the hy-droxy groups of the ligand and the nitrate anion.

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