Display options
Cite
Cela-Pérez MC, Castro-López MM, Lasagabáster-Latorre A, et al. Synthesis and characterization of bisphenol-A imprinted polymer as a selective recognition receptor. Anal Chim Acta. 2011;706(2):275-84doi: 10.1016/j.aca.2011.09.002.
Cela-Pérez, M. C., Castro-López, M. M., Lasagabáster-Latorre, A., López-Vilariño, J. M., González-Rodríguez, M. V., & Barral-Losada, L. F. (2011). Synthesis and characterization of bisphenol-A imprinted polymer as a selective recognition receptor. Analytica chimica acta, 706(2), 275-84. https://doi.org/10.1016/j.aca.2011.09.002
Cela-Pérez, M C, et al. "Synthesis and characterization of bisphenol-A imprinted polymer as a selective recognition receptor." Analytica chimica acta vol. 706,2 (2011): 275-84. doi: https://doi.org/10.1016/j.aca.2011.09.002
Cela-Pérez MC, Castro-López MM, Lasagabáster-Latorre A, López-Vilariño JM, González-Rodríguez MV, Barral-Losada LF. Synthesis and characterization of bisphenol-A imprinted polymer as a selective recognition receptor. Anal Chim Acta. 2011 Nov 14;706(2):275-84. doi: 10.1016/j.aca.2011.09.002. Epub 2011 Sep 09. PMID: 22023862.
Copy Download .nbib Format: NLM
Share it on

Anal Chim Acta. 2011 Nov 14;706(2):275-84. doi: 10.1016/j.aca.2011.09.002. Epub 2011 Sep 09.

Synthesis and characterization of bisphenol-A imprinted polymer as a selective recognition receptor.

Analytica chimica acta

M C Cela-Pérez, M M Castro-López, A Lasagabáster-Latorre, J M López-Vilariño, M V González-Rodríguez, L F Barral-Losada

Affiliations

  1. Laboratorio de Química, Centro de Investigacións Tecnolóxicas, Universidade da Coruña, Campus de Esteiro s/n, Ferrol 15403, Spain. [email protected]

PMID: 22023862 DOI: 10.1016/j.aca.2011.09.002

Abstract

Molecularly imprinted polymers (MIPs) are currently used to provide selectivity in chemical sensors. In this context, a non-covalent bisphenol-A (BPA)-imprinted polymer using 4-vinylpyridine (4-Vpy) as the functional monomer, ethylene glycol dimethacrylate (EGDMA) as crosslinker and a low volatile solvent, triethylene glycol dimethyl ether (TRIGLYME), in combination with a non-reactive linear polymer, poly (vinyl acetate) (PVAc), as porogen, was synthesized with a simple polymerization procedure. Batch rebinding experiments were carried out to evaluate the binding and selectivity properties of the BPA-MIP. The experimental adsorption isotherms were fitted and a heterogeneous distribution of the binding sites was found. The selectivity of MIP demonstrated higher affinity for target BPA and BPA-analogues over other common water pollutants. The adsorption kinetics followed the pseudo-second-order kinetic model so that the specific adsorption in the imprinted cavities by two strong hydrogen bonds could be described as a chemisorption process. The diffusion mechanism was determined by the intra-particle diffusion and Boyd models, both of them revealing that the adsorption was mainly governed by intra-particle diffusion. MIP was shown to be promising for regeneration without significant loss in adsorption capacity.

Copyright © 2011 Elsevier B.V. All rights reserved.

Publication Types