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Forfar LC, Clark TJ, Green M, et al. White phosphorus as a ligand for the coinage metals. Chem Commun (Camb). 2012;48(14):1970-2doi: 10.1039/c2cc15291f.
Forfar, L. C., Clark, T. J., Green, M., Mansell, S. M., Russell, C. A., Sanguramath, R. A., & Slattery, J. M. (2012). White phosphorus as a ligand for the coinage metals. Chemical communications (Cambridge, England), 48(14), 1970-2. https://doi.org/10.1039/c2cc15291f
Forfar, Laura C, et al. "White phosphorus as a ligand for the coinage metals." Chemical communications (Cambridge, England) vol. 48,14 (2012): 1970-2. doi: https://doi.org/10.1039/c2cc15291f
Forfar LC, Clark TJ, Green M, Mansell SM, Russell CA, Sanguramath RA, Slattery JM. White phosphorus as a ligand for the coinage metals. Chem Commun (Camb). 2012 Feb 14;48(14):1970-2. doi: 10.1039/c2cc15291f. Epub 2012 Jan 11. PMID: 22234580.
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Chem Commun (Camb). 2012 Feb 14;48(14):1970-2. doi: 10.1039/c2cc15291f. Epub 2012 Jan 11.

White phosphorus as a ligand for the coinage metals.

Chemical communications (Cambridge, England)

Laura C Forfar, Timothy J Clark, Michael Green, Stephen M Mansell, Christopher A Russell, Rajashekharayya A Sanguramath, John M Slattery

Affiliations

  1. School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK.

PMID: 22234580 DOI: 10.1039/c2cc15291f

Abstract

Reaction of equimolar quantities of MX (M = Au, Cu, X = Cl; M = Ag, X = OTf) and GaCl(3) in CH(2)Cl(2) with P(4) leads to phosphorus ligating a cationic coinage metal centre. For Cu and Ag, ion-contacted coordination polymers are formed; for Au, an ion-separated complex is observed that features the [Au(η(2)-P(4))(2)](+) cation, which is the first homoleptic Au-P(4) complex to be characterised in the condensed phase.

This journal is © The Royal Society of Chemistry 2012

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