Display options
Cite
Fabregat G, Alemán C, Casas MT, et al. Controlling the morphology of poly(N-cyanoethylpyrrole). J Phys Chem B. 2012;116(16):5064-70doi: 10.1021/jp3008688.
Fabregat, G., Alemán, C., Casas, M. T., & Armelin, E. (2012). Controlling the morphology of poly(N-cyanoethylpyrrole). The journal of physical chemistry. B, 116(16), 5064-70. https://doi.org/10.1021/jp3008688
Fabregat, Georgina, et al. "Controlling the morphology of poly(N-cyanoethylpyrrole)." The journal of physical chemistry. B vol. 116,16 (2012): 5064-70. doi: https://doi.org/10.1021/jp3008688
Fabregat G, Alemán C, Casas MT, Armelin E. Controlling the morphology of poly(N-cyanoethylpyrrole). J Phys Chem B. 2012 Apr 26;116(16):5064-70. doi: 10.1021/jp3008688. Epub 2012 Apr 13. PMID: 22497587.
Copy Download .nbib Format: NLM
Share it on

J Phys Chem B. 2012 Apr 26;116(16):5064-70. doi: 10.1021/jp3008688. Epub 2012 Apr 13.

Controlling the morphology of poly(N-cyanoethylpyrrole).

The journal of physical chemistry. B

Georgina Fabregat, Carlos Alemán, Maria T Casas, Elaine Armelin

Affiliations

  1. Departament d'Enginyeria Química, ETSEIB, Universitat Politècnica de Catalunya , Av. Diagonal 647, 08028, Barcelona, Spain.

PMID: 22497587 DOI: 10.1021/jp3008688

Abstract

The morphology of poly(N-cyanoethylpyrrole) has been controlled through the polymerization process. This polymer has been prepared by anodic polymerization, chemical oxidative polymerization in emulsion medium, and layer-by-layer templating polymerization. Anodic polymerization using LiClO4 as supporting electrolyte provides compact films, in which the oxidation degree is controlled through the thickness, useful for the microdetection of dopamine. Chemical polymerization using FeCl3 as oxidant agent results in very well-defined microspheres with porous internal structure, which may be useful in molecular loading and transport processes. Finally, the layer-by-layer templating technique produces core-shell particles of controlled size and thickness. Moreover, these core-shell particles can be easily converted in hollow microspheres by removing the template.

Publication Types