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Rivera-Fuentes P, Rekowski Mv, Schweizer WB, et al. Cascade carbopalladation reaction between alkynes and gem-dibromoolefins: facile access to monoannelated pentalenes. Org Lett. 2012;14(16):4066-9doi: 10.1021/ol301670d.
Rivera-Fuentes, P., Rekowski, M. v., Schweizer, W. B., Gisselbrecht, J. P., Boudon, C., & Diederich, F. (2012). Cascade carbopalladation reaction between alkynes and gem-dibromoolefins: facile access to monoannelated pentalenes. Organic letters, 14(16), 4066-9. https://doi.org/10.1021/ol301670d
Rivera-Fuentes, Pablo, et al. "Cascade carbopalladation reaction between alkynes and gem-dibromoolefins: facile access to monoannelated pentalenes." Organic letters vol. 14,16 (2012): 4066-9. doi: https://doi.org/10.1021/ol301670d
Rivera-Fuentes P, Rekowski Mv, Schweizer WB, Gisselbrecht JP, Boudon C, Diederich F. Cascade carbopalladation reaction between alkynes and gem-dibromoolefins: facile access to monoannelated pentalenes. Org Lett. 2012 Aug 17;14(16):4066-9. doi: 10.1021/ol301670d. Epub 2012 Jul 31. PMID: 22849571.
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Org Lett. 2012 Aug 17;14(16):4066-9. doi: 10.1021/ol301670d. Epub 2012 Jul 31.

Cascade carbopalladation reaction between alkynes and gem-dibromoolefins: facile access to monoannelated pentalenes.

Organic letters

Pablo Rivera-Fuentes, Margarete von Wantoch Rekowski, W Bernd Schweizer, Jean-Paul Gisselbrecht, Corinne Boudon, François Diederich

Affiliations

  1. Laboratorium für Organische Chemie, ETH Zürich, Hönggerberg, HCI, 8093 Zürich, Switzerland.

PMID: 22849571 DOI: 10.1021/ol301670d

Abstract

A carbopalladation cascade reaction of easily accessible gem-dibromoolefins and alkynes furnishes monobenzo- and mononaphthopentalenes. The new chromophores accessed by this short route exhibit small HOMO-LUMO gaps and redox amphoteric behavior with tunable redox potentials.

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