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Rybakov VB, Belov DS, Lukyanenko ER, et al. (1R,3R,3aS,8aR)-4-Oxo-3-phenyl-1-[(1R)-1-phenyl-eth-yl]deca-hydro-cyclo-hepta-[b]pyrrol-1-ium bromide. Acta Crystallogr Sect E Struct Rep Online. 2012;68:o2227doi: 10.1107/S1600536812028073.
Rybakov, V. B., Belov, D. S., Lukyanenko, E. R., Kurkin, A. V., & Yurovskaya, M. A. (2012). (1R,3R,3aS,8aR)-4-Oxo-3-phenyl-1-[(1R)-1-phenyl-eth-yl]deca-hydro-cyclo-hepta-[b]pyrrol-1-ium bromide. Acta crystallographica. Section E, Structure reports online, 68o2227. https://doi.org/10.1107/S1600536812028073
Rybakov, Victor B, et al. "(1R,3R,3aS,8aR)-4-Oxo-3-phenyl-1-[(1R)-1-phenyl-eth-yl]deca-hydro-cyclo-hepta-[b]pyrrol-1-ium bromide." Acta crystallographica. Section E, Structure reports online vol. 68 (2012): o2227. doi: https://doi.org/10.1107/S1600536812028073
Rybakov VB, Belov DS, Lukyanenko ER, Kurkin AV, Yurovskaya MA. (1R,3R,3aS,8aR)-4-Oxo-3-phenyl-1-[(1R)-1-phenyl-eth-yl]deca-hydro-cyclo-hepta-[b]pyrrol-1-ium bromide. Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 01;68:o2227. doi: 10.1107/S1600536812028073. Epub 2012 Jun 27. PMID: 22798884; PMCID: PMC3394019.
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Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 01;68:o2227. doi: 10.1107/S1600536812028073. Epub 2012 Jun 27.

(1R,3R,3aS,8aR)-4-Oxo-3-phenyl-1-[(1R)-1-phenyl-eth-yl]deca-hydro-cyclo-hepta-[b]pyrrol-1-ium bromide.

Acta crystallographica. Section E, Structure reports online

Victor B Rybakov, Dmitry S Belov, Evgeny R Lukyanenko, Alexander V Kurkin, Marina A Yurovskaya

Affiliations

  1. Department of Chemistry, Moscow State University, 119992 Moscow, Russian Federation.

PMID: 22798884 PMCID: PMC3394019 DOI: 10.1107/S1600536812028073

Abstract

The title chiral compound, C(23)H(28)NO(+)·Br(-), was obtained from an optically active amino-ethanol precursor. The pyrrolidine heterocycle has an envelope conformation, with the C atom α-positioned with respect to the keto group deviating by 0.570 (6) Å from the mean plane of other atoms. The trans-fused seven-membered ring adopts a pseudo-chair conformation. The two phenyl rings form a dihedral angle of 85.1 (2)°. The cationic center and the bromide anion are connected through an N-H⋯Br hydrogen bond.

References

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