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Gee WJ, MacLellan JG, Forsyth CM, et al. Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster. Inorg Chem. 2012;51(16):8661-3doi: 10.1021/ic301382r.
Gee, W. J., MacLellan, J. G., Forsyth, C. M., Moubaraki, B., Murray, K. S., Andrews, P. C., & Junk, P. C. (2012). Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster. Inorganic chemistry, 51(16), 8661-3. https://doi.org/10.1021/ic301382r
Gee, William J, et al. "Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster." Inorganic chemistry vol. 51,16 (2012): 8661-3. doi: https://doi.org/10.1021/ic301382r
Gee WJ, MacLellan JG, Forsyth CM, Moubaraki B, Murray KS, Andrews PC, Junk PC. Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster. Inorg Chem. 2012 Aug 20;51(16):8661-3. doi: 10.1021/ic301382r. Epub 2012 Aug 02. PMID: 22857781.
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Inorg Chem. 2012 Aug 20;51(16):8661-3. doi: 10.1021/ic301382r. Epub 2012 Aug 02.

Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster.

Inorganic chemistry

William J Gee, Jonathan G MacLellan, Craig M Forsyth, Boujemaa Moubaraki, Keith S Murray, Philip C Andrews, Peter C Junk

Affiliations

  1. School of Chemistry, Monash University, Clayton, Victoria 3800, Australia.

PMID: 22857781 DOI: 10.1021/ic301382r

Abstract

Sequestration of peroxide derived from molecular oxygen has resulted in the templated synthesis of a terbium picolinate cluster, isolated as a 2D sodiated network in the solid state. This first example of an air-stable rare-earth peroxide cluster represents key evidence for a peroxide-containing intermediate in rare-earth-cluster-catalyzed oxidation reactions. Luminescent and magnetic properties have also been investigated.

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