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Hartmann S, Wittko G, Köhler W, et al. Thermophobicity of liquids: heats of transport in mixtures as pure component properties. Phys Rev Lett. 2012;109(6):065901doi: 10.1103/PhysRevLett.109.065901.
Hartmann, S., Wittko, G., Köhler, W., Morozov, K. I., Albers, K., & Sadowski, G. (2012). Thermophobicity of liquids: heats of transport in mixtures as pure component properties. Physical review letters, 109(6), 065901. https://doi.org/10.1103/PhysRevLett.109.065901
Hartmann, S, et al. "Thermophobicity of liquids: heats of transport in mixtures as pure component properties." Physical review letters vol. 109,6 (2012): 065901. doi: https://doi.org/10.1103/PhysRevLett.109.065901
Hartmann S, Wittko G, Köhler W, Morozov KI, Albers K, Sadowski G. Thermophobicity of liquids: heats of transport in mixtures as pure component properties. Phys Rev Lett. 2012 Aug 10;109(6):065901. doi: 10.1103/PhysRevLett.109.065901. Epub 2012 Aug 10. PMID: 23006282.
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Phys Rev Lett. 2012 Aug 10;109(6):065901. doi: 10.1103/PhysRevLett.109.065901. Epub 2012 Aug 10.

Thermophobicity of liquids: heats of transport in mixtures as pure component properties.

Physical review letters

S Hartmann, G Wittko, W Köhler, K I Morozov, K Albers, G Sadowski

Affiliations

  1. Physikalisches Institut, Universität Bayreuth, D-95440 Bayreuth, Germany.

PMID: 23006282 DOI: 10.1103/PhysRevLett.109.065901

Abstract

We have measured the Soret coefficients of 41 out of 45 possible equimolar binary mixtures of 10 different organic solvents and found an additive rule for the heats of transport. These can, except for an undetermined offset, uniquely be assigned to the pure components. Based on their heats of transport, the fluids can be arranged according to their thermophobicity, similar to the standard electrode potential. A qualitative explanation of this unexpected additivity is based on the work of Morozov [Phys. Rev. E 79, 031204 (2009)].

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