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Org Lett. 2012 Dec 21;14(24):6206-9. doi: 10.1021/ol302956s. Epub 2012 Dec 04.

Ruthenium-catalyzed C-H bond oxygenations with weakly coordinating ketones.

Organic letters

Vedhagiri S Thirunavukkarasu, Lutz Ackermann

Affiliations

  1. Institut für Organische und Biomolekulare Chemie, Georg-August-Universität, Tammannstrasse 2, 37077 Göttingen, Germany.

PMID: 23210732 DOI: 10.1021/ol302956s

Abstract

Ruthenium complexes enabled first C(sp(2))-H bond oxygenations of aromatic ketones with excellent functional group tolerance, and broad scope as well as high chemoselectivity and site selectivity.

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