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Janczak J, Rubinger MM, Alves LC, et al. Poly[di-μ-aqua-[μ6-N-(4-bromophenylsulfonyl)dithiocarbimato]dipotassium] and poly[di-μ-aqua-[μ4-N-(4-iodophenylsulfonyl)dithiocarbimato]dipotassium]. Acta Crystallogr C. 2012;68:m312-6doi: 10.1107/S0108270112040589.
Janczak, J., Rubinger, M. M., Alves, L. C., & Oliveira, M. R. (2012). Poly[di-μ-aqua-[μ6-N-(4-bromophenylsulfonyl)dithiocarbimato]dipotassium] and poly[di-μ-aqua-[μ4-N-(4-iodophenylsulfonyl)dithiocarbimato]dipotassium]. Acta crystallographica. Section C, Crystal structure communications, 68m312-6. https://doi.org/10.1107/S0108270112040589
Janczak, Jan, et al. "Poly[di-μ-aqua-[μ6-N-(4-bromophenylsulfonyl)dithiocarbimato]dipotassium] and poly[di-μ-aqua-[μ4-N-(4-iodophenylsulfonyl)dithiocarbimato]dipotassium]." Acta crystallographica. Section C, Crystal structure communications vol. 68 (2012): m312-6. doi: https://doi.org/10.1107/S0108270112040589
Janczak J, Rubinger MM, Alves LC, Oliveira MR. Poly[di-μ-aqua-[μ6-N-(4-bromophenylsulfonyl)dithiocarbimato]dipotassium] and poly[di-μ-aqua-[μ4-N-(4-iodophenylsulfonyl)dithiocarbimato]dipotassium]. Acta Crystallogr C. 2012 Nov;68:m312-6. doi: 10.1107/S0108270112040589. Epub 2012 Oct 23. PMID: 23124451.
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Acta Crystallogr C. 2012 Nov;68:m312-6. doi: 10.1107/S0108270112040589. Epub 2012 Oct 23.

Poly[di-μ-aqua-[μ6-N-(4-bromophenylsulfonyl)dithiocarbimato]dipotassium] and poly[di-μ-aqua-[μ4-N-(4-iodophenylsulfonyl)dithiocarbimato]dipotassium].

Acta crystallographica. Section C, Crystal structure communications

Jan Janczak, Mayura M M Rubinger, Leandro C Alves, Marcelo R L Oliveira

Affiliations

  1. Institute of Low Temperature and Structure Research, Polish Academy of Sciences, PO Box 1410, 50-950 Wroc?aw, Poland. [email protected]

PMID: 23124451 DOI: 10.1107/S0108270112040589

Abstract

The rigid organic linkers N-(4-bromophenylsulfonyl)dithiocarbimate(2-) and N-(4-iodophenylsulfonyl)dithiocarbimate(2-) crystallize with two potassium cations and two water molecules in their asymmetric units, forming the title coordination polymers, [K(2)(C(7)H(4)BrNO(2)S(3))(H(2)O)(2)](n) and [K(2)(C(7)H(4)INO(2)S(3))(H(2)O)(2)](n). The anions and the water molecules link the potassium cations into broad two-dimensional networks, which are further linked by K···halide interactions.

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