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Gatineau D, Zhao Q, Curran DP, et al. N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation. Dalton Trans. 2013;42(20):7458-62doi: 10.1039/c3dt32983f.
Gatineau, D., Zhao, Q., Curran, D. P., Malacria, M., Lacôte, E., Fensterbank, L., & Goddard, J. P. (2013). N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation. Dalton transactions (Cambridge, England : 2003), 42(20), 7458-62. https://doi.org/10.1039/c3dt32983f
Gatineau, David, et al. "N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation." Dalton transactions (Cambridge, England : 2003) vol. 42,20 (2013): 7458-62. doi: https://doi.org/10.1039/c3dt32983f
Gatineau D, Zhao Q, Curran DP, Malacria M, Lacôte E, Fensterbank L, Goddard JP. N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation. Dalton Trans. 2013 May 28;42(20):7458-62. doi: 10.1039/c3dt32983f. PMID: 23459715.
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Dalton Trans. 2013 May 28;42(20):7458-62. doi: 10.1039/c3dt32983f.

N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation.

Dalton transactions (Cambridge, England : 2003)

David Gatineau, Qiwu Zhao, Dennis P Curran, Max Malacria, Emmanuel Lacôte, Louis Fensterbank, Jean-Philippe Goddard

Affiliations

  1. Institut Parisien de Chimie Moléculaire (UMR CNRS 7201)-FR 2769 UPMC Univ Paris 06, 4 place Jussieu, C. 229, 75005 Paris, France.

PMID: 23459715 DOI: 10.1039/c3dt32983f

Abstract

Investigation of the mechanism of the NHC-initiated hydrosilylation of styryl alcohols in the presence of a dihydrosilane suggests a general base catalysis mechanism and not the activation of the dihydrosilane by the NHC.

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