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Yan Y, Remhof A, Rentsch D, et al. Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?. Chem Commun (Camb). 2013;49(45):5234-6doi: 10.1039/c3cc41184b.
Yan, Y., Remhof, A., Rentsch, D., Lee, Y. S., Whan Cho, Y., & Züttel, A. (2013). Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?. Chemical communications (Cambridge, England), 49(45), 5234-6. https://doi.org/10.1039/c3cc41184b
Yan, Yigang, et al. "Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?." Chemical communications (Cambridge, England) vol. 49,45 (2013): 5234-6. doi: https://doi.org/10.1039/c3cc41184b
Yan Y, Remhof A, Rentsch D, Lee YS, Whan Cho Y, Züttel A. Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?. Chem Commun (Camb). 2013 Jun 07;49(45):5234-6. doi: 10.1039/c3cc41184b. PMID: 23628977.
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Chem Commun (Camb). 2013 Jun 07;49(45):5234-6. doi: 10.1039/c3cc41184b.

Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?.

Chemical communications (Cambridge, England)

Yigang Yan, Arndt Remhof, Daniel Rentsch, Young-Su Lee, Young Whan Cho, Andreas Züttel

Affiliations

  1. EMPA, Swiss Federal Laboratories for Materials Science and Technology, Hydrogen & Energy, 8600 Dübendorf, Switzerland. [email protected]

PMID: 23628977 DOI: 10.1039/c3cc41184b

Abstract

Dodecaborates, i.e. the [B12H12](2-) containing species, are often observed as main intermediates in the hydrogen sorption cycle of metal borohydrides, hindering rehydrogenation. In the decomposition process of Y(BH4)3, yttrium octahydrotriborate, i.e. Y(B3H8)3, rather than the stable Y2(B12H12)3, is formed as the main intermediate.

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