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Thirunavukkarasu VS, Raghuvanshi K, Ackermann L. Expedient C-H amidations of heteroaryl arenes catalyzed by versatile ruthenium(II) catalysts. Org Lett. 2013;15(13):3286-9doi: 10.1021/ol401321q.
Thirunavukkarasu, V. S., Raghuvanshi, K., & Ackermann, L. (2013). Expedient C-H amidations of heteroaryl arenes catalyzed by versatile ruthenium(II) catalysts. Organic letters, 15(13), 3286-9. https://doi.org/10.1021/ol401321q
Thirunavukkarasu, Vedhagiri S, et al. "Expedient C-H amidations of heteroaryl arenes catalyzed by versatile ruthenium(II) catalysts." Organic letters vol. 15,13 (2013): 3286-9. doi: https://doi.org/10.1021/ol401321q
Thirunavukkarasu VS, Raghuvanshi K, Ackermann L. Expedient C-H amidations of heteroaryl arenes catalyzed by versatile ruthenium(II) catalysts. Org Lett. 2013 Jul 05;15(13):3286-9. doi: 10.1021/ol401321q. Epub 2013 Jun 14. PMID: 23767780.
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Org Lett. 2013 Jul 05;15(13):3286-9. doi: 10.1021/ol401321q. Epub 2013 Jun 14.

Expedient C-H amidations of heteroaryl arenes catalyzed by versatile ruthenium(II) catalysts.

Organic letters

Vedhagiri S Thirunavukkarasu, Keshav Raghuvanshi, Lutz Ackermann

Affiliations

  1. Institut für Organische und Biomolekulare Chemie, Georg-August-Universität, Tammannstr. 2, 37077 Göttingen, Germany.

PMID: 23767780 DOI: 10.1021/ol401321q

Abstract

Heteroaryl-substituted arenes and heteroarenes were efficiently amidated through ruthenium-catalyzed C-H bond functionalizations with a variety of sulfonyl azides. Particularly, cationic ruthenium(II) complexes proved to be most effective and allowed nitrogenations of electron-rich and electron-deficient arenes with ample substrate scope.

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