Display options
Cite
Seidel RW, Ganesamoorthy C, Loerke S, et al. catena-Poly[[(tetrahydrofuran-κO)potassium]-μ-(η5:η5)-2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl]. Acta Crystallogr C. 2013;69:573-6doi: 10.1107/S0108270113011074.
Seidel, R. W., Ganesamoorthy, C., Loerke, S., Winter, M. V., Gemel, C., & Fischer, R. A. (2013). catena-Poly[[(tetrahydrofuran-κO)potassium]-μ-(η5:η5)-2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl]. Acta crystallographica. Section C, Crystal structure communications, 69573-6. https://doi.org/10.1107/S0108270113011074
Seidel, Rüdiger W, et al. "catena-Poly[[(tetrahydrofuran-κO)potassium]-μ-(η5:η5)-2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl]." Acta crystallographica. Section C, Crystal structure communications vol. 69 (2013): 573-6. doi: https://doi.org/10.1107/S0108270113011074
Seidel RW, Ganesamoorthy C, Loerke S, Winter MV, Gemel C, Fischer RA. catena-Poly[[(tetrahydrofuran-κO)potassium]-μ-(η5:η5)-2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl]. Acta Crystallogr C. 2013 Jun;69:573-6. doi: 10.1107/S0108270113011074. Epub 2013 May 02. PMID: 23744369.
Copy Download .nbib Format: NLM
Share it on

Acta Crystallogr C. 2013 Jun;69:573-6. doi: 10.1107/S0108270113011074. Epub 2013 May 02.

catena-Poly[[(tetrahydrofuran-κO)potassium]-μ-(η5:η5)-2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl].

Acta crystallographica. Section C, Crystal structure communications

Rüdiger W Seidel, Chelladurai Ganesamoorthy, Sinah Loerke, Manuela V Winter, Christian Gemel, Roland A Fischer

Affiliations

  1. Lehrstuhl für Analytische Chemie, Ruhr-Universität Bochum, Universitätsstrasse 150, 44780 Bochum, Germany. [email protected]

PMID: 23744369 DOI: 10.1107/S0108270113011074

Abstract

The title compound, [K(C14H23)(C4H8O)]n, comprises zigzag chains of alternating bridging 2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl ligands and potassium ions, with an ancillary tetrahydrofuran ligand in the coordination environment of potassium. The coordination polymer strands so formed extend by 21 screw symmetry in the b-axis direction. The chemically modified cyclopentadienyl ligand, with a tethered n-pentyl group, was synthesized from 2,3,4,5-tetramethylcyclopent-2-enone by a Grignard reaction.

Publication Types