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Schubert C, Rudolf M, Guldi DM, et al. Rates and energetics of intramolecular electron transfer processes in conjugated metallofullerenes. Philos Trans A Math Phys Eng Sci. 2013;371(1998):20120490doi: 10.1098/rsta.2012.0490.
Schubert, C., Rudolf, M., Guldi, D. M., Takano, Y., Mizorogi, N., Herranz, M. �. �., Martín, N., Nagase, S., & Akasaka, T. (2013). Rates and energetics of intramolecular electron transfer processes in conjugated metallofullerenes. Philosophical transactions. Series A, Mathematical, physical, and engineering sciences, 371(1998), 20120490. https://doi.org/10.1098/rsta.2012.0490
Schubert, Christina, et al. "Rates and energetics of intramolecular electron transfer processes in conjugated metallofullerenes." Philosophical transactions. Series A, Mathematical, physical, and engineering sciences vol. 371,1998 (2013): 20120490. doi: https://doi.org/10.1098/rsta.2012.0490
Schubert C, Rudolf M, Guldi DM, Takano Y, Mizorogi N, Herranz MÁ, Martín N, Nagase S, Akasaka T. Rates and energetics of intramolecular electron transfer processes in conjugated metallofullerenes. Philos Trans A Math Phys Eng Sci. 2013 Aug 05;371(1998):20120490. doi: 10.1098/rsta.2012.0490. Print 2013 Sep 13. PMID: 23918719.
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Philos Trans A Math Phys Eng Sci. 2013 Aug 05;371(1998):20120490. doi: 10.1098/rsta.2012.0490. Print 2013 Sep 13.

Rates and energetics of intramolecular electron transfer processes in conjugated metallofullerenes.

Philosophical transactions. Series A, Mathematical, physical, and engineering sciences

Christina Schubert, Marc Rudolf, Dirk M Guldi, Yuta Takano, Naomi Mizorogi, M Ángeles Herranz, Nazario Martín, Shigeru Nagase, Takeshi Akasaka

Affiliations

  1. Department of Chemistry and Pharmacy, and Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen, Germany.

PMID: 23918719 DOI: 10.1098/rsta.2012.0490

Abstract

In this paper, we report on the design, redox potentials, excited state energies and radical ion pair state energies in electron donor-acceptor conjugates comprising the electron-donating π-extended tetrathiafulvalene and several electron-accepting fullerenes. To this end, we contrast an empty fullerene, that is, C₆₀, with two endohedral metallofullerenes, that is, open-shell La@C₈₂ and closed-shell La₂@C₈₀, in terms of charge separation and charge recombination dynamics.

Keywords: electron transfer; fullerene; metallofullerene

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