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Chem Commun (Camb). 2013 Nov 18;49(89):10459-61. doi: 10.1039/c3cc43384f.

One-dimensional alignment of strong Lewis acid sites in a porous coordination polymer.

Chemical communications (Cambridge, England)

Takashi Kajiwara, Masakazu Higuchi, Akihiro Yuasa, Hideyuki Higashimura, Susumu Kitagawa

Affiliations

  1. Advanced Materials Research Laboratory, Sumitomo Chemical Co., Ltd., 6 Kitahara, Tsukuba, Ibaraki 300-3294, Japan. [email protected].

PMID: 23872698 DOI: 10.1039/c3cc43384f

Abstract

A new lanthanoid porous coordination polymer, La-BTTc (BTTc = benzene-1,3,5-tris(2-thiophene-5-carboxylate)), was synthesized and structurally characterized to have densely aligned one-dimensional open metal sites, which were found to act as strong Lewis acid sites after the removal of the coordinated solvent.

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