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Fendt F, Koch C, Gärtner S, et al. Reaction of Sn4(4-) in liquid ammonia: the formation of Rb6[(η2-Sn4)Zn(η3-Sn4)]·5NH3. Dalton Trans. 2013;42(44):15548-50doi: 10.1039/c3dt51932e.
Fendt, F., Koch, C., Gärtner, S., & Korber, N. (2013). Reaction of Sn4(4-) in liquid ammonia: the formation of Rb6[(η2-Sn4)Zn(η3-Sn4)]·5NH3. Dalton transactions (Cambridge, England : 2003), 42(44), 15548-50. https://doi.org/10.1039/c3dt51932e
Fendt, Franziska, et al. "Reaction of Sn4(4-) in liquid ammonia: the formation of Rb6[(η2-Sn4)Zn(η3-Sn4)]·5NH3." Dalton transactions (Cambridge, England : 2003) vol. 42,44 (2013): 15548-50. doi: https://doi.org/10.1039/c3dt51932e
Fendt F, Koch C, Gärtner S, Korber N. Reaction of Sn4(4-) in liquid ammonia: the formation of Rb6[(η2-Sn4)Zn(η3-Sn4)]·5NH3. Dalton Trans. 2013 Nov 28;42(44):15548-50. doi: 10.1039/c3dt51932e. PMID: 24067942.
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Dalton Trans. 2013 Nov 28;42(44):15548-50. doi: 10.1039/c3dt51932e.

Reaction of Sn4(4-) in liquid ammonia: the formation of Rb6[(η2-Sn4)Zn(η3-Sn4)]·5NH3.

Dalton transactions (Cambridge, England : 2003)

Franziska Fendt, Carina Koch, Stefanie Gärtner, Nikolaus Korber

Affiliations

  1. Institute of Inorganic Chemistry, University of Regensburg, Universitätsstr. 31, 93053 Regensburg, Germany. [email protected].

PMID: 24067942 DOI: 10.1039/c3dt51932e

Abstract

The reaction of Rb4Sn4 with ZnPh2 in liquid ammonia in the presence of [2.2.2]-cryptand yielded crystals of Rb6[(η(2)-Sn4)Zn(η(3)-Sn4)]·5NH3, which could be characterized by single crystal X-ray diffraction. This is the first example of a successful solution reaction of the highly charged tetrahedral Sn4(4-) anions. The homoleptic [E4ZnE4](6-) complex (E = tetrel element) was previously known only for E=Ge and Si/Ge.

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