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Rubino FM, Banfi S, Pozzi G, et al. A study on the solution and gas-phase chemistry of Mn(III) and Fe(III) tetraarylporphyrin complexes by fast-atom bombardment mass spectrometry : 2: Synthesis and characterization of molecular complexes federico maria rubino. J Am Soc Mass Spectrom. 1993;4(3):255-8doi: 10.1016/1044-0305(93)85089-G.
Rubino, F. M., Banfi, S., Pozzi, G., & Quici, S. (1993). A study on the solution and gas-phase chemistry of Mn(III) and Fe(III) tetraarylporphyrin complexes by fast-atom bombardment mass spectrometry : 2: Synthesis and characterization of molecular complexes federico maria rubino. Journal of the American Society for Mass Spectrometry, 4(3), 255-8. https://doi.org/10.1016/1044-0305(93)85089-G
Rubino, F M, et al. "A study on the solution and gas-phase chemistry of Mn(III) and Fe(III) tetraarylporphyrin complexes by fast-atom bombardment mass spectrometry : 2: Synthesis and characterization of molecular complexes federico maria rubino." Journal of the American Society for Mass Spectrometry vol. 4,3 (1993): 255-8. doi: https://doi.org/10.1016/1044-0305(93)85089-G
Rubino FM, Banfi S, Pozzi G, Quici S. A study on the solution and gas-phase chemistry of Mn(III) and Fe(III) tetraarylporphyrin complexes by fast-atom bombardment mass spectrometry : 2: Synthesis and characterization of molecular complexes federico maria rubino. J Am Soc Mass Spectrom. 1993 Mar;4(3):255-8. doi: 10.1016/1044-0305(93)85089-G. PMID: 24234855.
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J Am Soc Mass Spectrom. 1993 Mar;4(3):255-8. doi: 10.1016/1044-0305(93)85089-G.

A study on the solution and gas-phase chemistry of Mn(III) and Fe(III) tetraarylporphyrin complexes by fast-atom bombardment mass spectrometry : 2: Synthesis and characterization of molecular complexes federico maria rubino.

Journal of the American Society for Mass Spectrometry

F M Rubino, S Banfi, G Pozzi, S Quici

Affiliations

  1. ITBA-CNR, v. Ampere 56, I-20131, Milan, Italy.

PMID: 24234855 DOI: 10.1016/1044-0305(93)85089-G

Abstract

The chemical behavior of Fe(III) and M(III) tetraarylporphorin (TAP) complexes with N-alkylimidazoles and other suitable ligands was studied by direct reaction in the fast-atom bombardment matrix and in the gas phase. The coordination reaction occurs at the metal center and yields molecular adducts of porphyry/ligand (PL) and PL, stoichiometry. Coordinative competition between free and covalently linked ligands can be used to probe the conformation of "tailed" Mn(III)-TAP.

References

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