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Yang XF, Li XH, Ding CH, et al. Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity. Chem Commun (Camb). 2014;50(4):484-6doi: 10.1039/c3cc46574h.
Yang, X. F., Li, X. H., Ding, C. H., Xu, C. F., Dai, L. X., & Hou, X. L. (2014). Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity. Chemical communications (Cambridge, England), 50(4), 484-6. https://doi.org/10.1039/c3cc46574h
Yang, Xiao-Fei, et al. "Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity." Chemical communications (Cambridge, England) vol. 50,4 (2014): 484-6. doi: https://doi.org/10.1039/c3cc46574h
Yang XF, Li XH, Ding CH, Xu CF, Dai LX, Hou XL. Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity. Chem Commun (Camb). 2014 Jan 14;50(4):484-6. doi: 10.1039/c3cc46574h. PMID: 24266021.
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Chem Commun (Camb). 2014 Jan 14;50(4):484-6. doi: 10.1039/c3cc46574h.

Pd-catalyzed allylic alkylation of dienyl carbonates with nitromethane with high C-5 regioselectivity.

Chemical communications (Cambridge, England)

Xiao-Fei Yang, Xiao-Hui Li, Chang-Hua Ding, Chao-Fan Xu, Li-Xin Dai, Xue-Long Hou

Affiliations

  1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry (SIOC), Chinese Academy of Sciences (CAS), 345 Lingling Road, Shanghai 200032, China. [email protected] [email protected].

PMID: 24266021 DOI: 10.1039/c3cc46574h

Abstract

A highly regioselective palladium-catalyzed allylic alkylation of dienyl esters with nitromethane has been developed, providing selective access to the C-5 attacked products. The structures of the ligands as well as the steric effect of the substrates are important factors in determining the regiochemical outcome of the reaction.

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