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Sipior J, Teh CK, Sulkes M. Solvent complexes of jet-cooled β-phenylethylamine. J Fluoresc. 1991;1(1):41-5doi: 10.1007/BF00865257.
Sipior, J., Teh, C. K., & Sulkes, M. (1991). Solvent complexes of jet-cooled β-phenylethylamine. Journal of fluorescence, 1(1), 41-5. https://doi.org/10.1007/BF00865257
Sipior, J, et al. "Solvent complexes of jet-cooled β-phenylethylamine." Journal of fluorescence vol. 1,1 (1991): 41-5. doi: https://doi.org/10.1007/BF00865257
Sipior J, Teh CK, Sulkes M. Solvent complexes of jet-cooled β-phenylethylamine. J Fluoresc. 1991 Mar;1(1):41-5. doi: 10.1007/BF00865257. PMID: 24242909.
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J Fluoresc. 1991 Mar;1(1):41-5. doi: 10.1007/BF00865257.

Solvent complexes of jet-cooled β-phenylethylamine.

Journal of fluorescence

J Sipior, C K Teh, M Sulkes

Affiliations

  1. Chemistry Department, Tulane University, 70118, New Orleans, Louisiana.

PMID: 24242909 DOI: 10.1007/BF00865257

Abstract

Laser-induced fluorescence spectroscopy was used to investigate β-phenylethylamine molecules that were cooled via supersonic gas expansions. The bare molecule spectra reveal 0-0 transitions that can be attributed to four separate conformers. Upon the addition of water or alcohol solvents, a series of new peaks is induced that appear to be built off separate bare molecule transitions. This is a pattern that is markedly different from the one seen for solvent addition to tyramine, which includes an-OH in the para position. As a result, definite hypotheses can be made to explain the influence of the para-OH in affecting solvent induced conformations.

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