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Baklanova YV, Denisova TA, Maksimova LG, et al. Synthesis and characterisation of new MO(OH)2 (M = Zr, Hf) oxyhydroxides and related Li2MO3 salts. Dalton Trans. 2014;43(7):2755-63doi: 10.1039/c3dt52929k.
Baklanova, Y. V., Denisova, T. A., Maksimova, L. G., Tyutyunnik, A. P., Baklanova, I. V., Shein, I. R., Neder, R. B., & Tarakina, N. V. (2014). Synthesis and characterisation of new MO(OH)2 (M = Zr, Hf) oxyhydroxides and related Li2MO3 salts. Dalton transactions (Cambridge, England : 2003), 43(7), 2755-63. https://doi.org/10.1039/c3dt52929k
Baklanova, Yana V, et al. "Synthesis and characterisation of new MO(OH)2 (M = Zr, Hf) oxyhydroxides and related Li2MO3 salts." Dalton transactions (Cambridge, England : 2003) vol. 43,7 (2014): 2755-63. doi: https://doi.org/10.1039/c3dt52929k
Baklanova YV, Denisova TA, Maksimova LG, Tyutyunnik AP, Baklanova IV, Shein IR, Neder RB, Tarakina NV. Synthesis and characterisation of new MO(OH)2 (M = Zr, Hf) oxyhydroxides and related Li2MO3 salts. Dalton Trans. 2014 Feb 21;43(7):2755-63. doi: 10.1039/c3dt52929k. PMID: 24343584.
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Dalton Trans. 2014 Feb 21;43(7):2755-63. doi: 10.1039/c3dt52929k.

Synthesis and characterisation of new MO(OH)2 (M = Zr, Hf) oxyhydroxides and related Li2MO3 salts.

Dalton transactions (Cambridge, England : 2003)

Yana V Baklanova, Tatyana A Denisova, Lidiya G Maksimova, Alexander P Tyutyunnik, Inna V Baklanova, Igor R Shein, Reinhard B Neder, Nadezda V Tarakina

Affiliations

  1. Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomayskaya str, 620990, Ekaterinburg, Russia. [email protected].

PMID: 24343584 DOI: 10.1039/c3dt52929k

Abstract

Two new solid MO(OH)2 (M = Zr, Hf) oxyhydroxides have been synthesised by an ion-exchange reaction from Li2MO3 (M = Zr, Hf) precursors obtained by a citrate combustion technique. The crystal structure of the oxyhydroxides has been solved by direct methods and refined using Rietveld full profile fitting based on X-ray powder diffraction data. Both oxyhydroxides crystallize in a P2(1)/c monoclinic unit cell and have a structure resembling that of the related salts. Detailed characterisation of the fine-structure features and chemical bonding in precursors and oxyhydroxide powders has been performed using vibrational spectroscopy, nuclear magnetic resonance spectroscopy, scanning electron microscopy, pair distribution function analysis and quantum-chemical modelling.

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