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Nihei T, Yokotani S, Ishihara T, et al. Stereocontrolled generation of nucleophilic (Z)- or (E)-α-fluoroalkenylchromium reagents via carbon-fluorine bond activation: highly stereoselective synthesis of (E)- or (Z)-β-fluoroallylic alcohols. Chem Commun (Camb). 2014;50(13):1543-5doi: 10.1039/c3cc47219a.
Nihei, T., Yokotani, S., Ishihara, T., & Konno, T. (2014). Stereocontrolled generation of nucleophilic (Z)- or (E)-α-fluoroalkenylchromium reagents via carbon-fluorine bond activation: highly stereoselective synthesis of (E)- or (Z)-β-fluoroallylic alcohols. Chemical communications (Cambridge, England), 50(13), 1543-5. https://doi.org/10.1039/c3cc47219a
Nihei, Takashi, et al. "Stereocontrolled generation of nucleophilic (Z)- or (E)-α-fluoroalkenylchromium reagents via carbon-fluorine bond activation: highly stereoselective synthesis of (E)- or (Z)-β-fluoroallylic alcohols." Chemical communications (Cambridge, England) vol. 50,13 (2014): 1543-5. doi: https://doi.org/10.1039/c3cc47219a
Nihei T, Yokotani S, Ishihara T, Konno T. Stereocontrolled generation of nucleophilic (Z)- or (E)-α-fluoroalkenylchromium reagents via carbon-fluorine bond activation: highly stereoselective synthesis of (E)- or (Z)-β-fluoroallylic alcohols. Chem Commun (Camb). 2014 Feb 14;50(13):1543-5. doi: 10.1039/c3cc47219a. PMID: 24382421.
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Chem Commun (Camb). 2014 Feb 14;50(13):1543-5. doi: 10.1039/c3cc47219a.

Stereocontrolled generation of nucleophilic (Z)- or (E)-α-fluoroalkenylchromium reagents via carbon-fluorine bond activation: highly stereoselective synthesis of (E)- or (Z)-β-fluoroallylic alcohols.

Chemical communications (Cambridge, England)

Takashi Nihei, Saya Yokotani, Takashi Ishihara, Tsutomu Konno

Affiliations

  1. Department of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan. [email protected].

PMID: 24382421 DOI: 10.1039/c3cc47219a

Abstract

Highly nucleophilic (Z)- or (E)-α-fluoroalkenylchromium species could be generated in a stereoselective manner via C-F bond activation of CBrF2-containing molecules, and they reacted smoothly with various aldehydes to give (E)- or (Z)-β-fluoroallylic alcohol derivatives in high yields, respectively.

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