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Chen WC, Lee CY, Lin BC, et al. The elusive three-coordinate dicationic hydrido boron complex. J Am Chem Soc. 2014;136(3):914-7doi: 10.1021/ja4120852.
Chen, W. C., Lee, C. Y., Lin, B. C., Hsu, Y. C., Shen, J. S., Hsu, C. P., Yap, G. P., & Ong, T. G. (2014). The elusive three-coordinate dicationic hydrido boron complex. Journal of the American Chemical Society, 136(3), 914-7. https://doi.org/10.1021/ja4120852
Chen, Wen-Ching, et al. "The elusive three-coordinate dicationic hydrido boron complex." Journal of the American Chemical Society vol. 136,3 (2014): 914-7. doi: https://doi.org/10.1021/ja4120852
Chen WC, Lee CY, Lin BC, Hsu YC, Shen JS, Hsu CP, Yap GP, Ong TG. The elusive three-coordinate dicationic hydrido boron complex. J Am Chem Soc. 2014 Jan 22;136(3):914-7. doi: 10.1021/ja4120852. Epub 2014 Jan 10. PMID: 24383448.
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J Am Chem Soc. 2014 Jan 22;136(3):914-7. doi: 10.1021/ja4120852. Epub 2014 Jan 10.

The elusive three-coordinate dicationic hydrido boron complex.

Journal of the American Chemical Society

Wen-Ching Chen, Ching-Yu Lee, Bo-Chao Lin, Yu-Chen Hsu, Jiun-Shian Shen, Chao-Ping Hsu, Glenn P A Yap, Tiow-Gan Ong

Affiliations

  1. Institute of Chemistry, Academia Sinica , Nangang, Taipei, Taiwan, Republic of China.

PMID: 24383448 DOI: 10.1021/ja4120852

Abstract

The formation of a hitherto unknown three-coordinate dicationic hydrido boron complex is described. Interestingly, supporting ligand carbodicarbene gave unprecedented reaction with BH3 without using more highly electrophilic Lewis acid precursors. Spectroscopic, crystallographic, and computational analysis was performed to understand the electronic features of these species.

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