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Hammer BA, Baumgarten M, Müllen K. Covalent attachment and release of small molecules from functional polyphenylene dendrimers. Chem Commun (Camb). 2014;50(16):2034-6doi: 10.1039/c3cc48741e.
Hammer, B. A., Baumgarten, M., & Müllen, K. (2014). Covalent attachment and release of small molecules from functional polyphenylene dendrimers. Chemical communications (Cambridge, England), 50(16), 2034-6. https://doi.org/10.1039/c3cc48741e
Hammer, Brenton A G, et al. "Covalent attachment and release of small molecules from functional polyphenylene dendrimers." Chemical communications (Cambridge, England) vol. 50,16 (2014): 2034-6. doi: https://doi.org/10.1039/c3cc48741e
Hammer BA, Baumgarten M, Müllen K. Covalent attachment and release of small molecules from functional polyphenylene dendrimers. Chem Commun (Camb). 2014 Feb 25;50(16):2034-6. doi: 10.1039/c3cc48741e. PMID: 24413634.
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Chem Commun (Camb). 2014 Feb 25;50(16):2034-6. doi: 10.1039/c3cc48741e.

Covalent attachment and release of small molecules from functional polyphenylene dendrimers.

Chemical communications (Cambridge, England)

Brenton A G Hammer, Martin Baumgarten, Klaus Müllen

Affiliations

  1. Max-Planck-Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz, Germany. [email protected].

PMID: 24413634 DOI: 10.1039/c3cc48741e

Abstract

Herein, we report the synthesis of 2nd generation PPDs functionalized with free thiol moieties within the scaffold, which were used as anchor points for the covalent attachment of guest species (p-nitrophenol derivatives) through the oxidative formation of disulfide linkages. The disulfide bonds were then cleaved under reductive conditions using dithiothreitol to discharge the molecules.

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