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Patterson MC, Keilbart ND, Kiruri LW, et al. EPFR Formation from Phenol adsorption on Al2O. Chem Phys. 2013;422:277-282doi: 10.1016/j.chemphys.2012.12.003.
Patterson, M. C., Keilbart, N. D., Kiruri, L. W., Thibodeaux, C. A., Lomnicki, S., Kurtz, R. L., Poliakoff, E. D., Dellinger, B., & Sprunger, P. T. (2013). EPFR Formation from Phenol adsorption on Al2O. Chemical physics, 422277-282. https://doi.org/10.1016/j.chemphys.2012.12.003
Patterson, Matthew C, et al. "EPFR Formation from Phenol adsorption on Al2O." Chemical physics vol. 422 (2013): 277-282. doi: https://doi.org/10.1016/j.chemphys.2012.12.003
Patterson MC, Keilbart ND, Kiruri LW, Thibodeaux CA, Lomnicki S, Kurtz RL, Poliakoff ED, Dellinger B, Sprunger PT. EPFR Formation from Phenol adsorption on Al2O. Chem Phys. 2013 Aug 30;422:277-282. doi: 10.1016/j.chemphys.2012.12.003. PMID: 24443627; PMCID: PMC3891583.
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Chem Phys. 2013 Aug 30;422:277-282. doi: 10.1016/j.chemphys.2012.12.003.

EPFR Formation from Phenol adsorption on Al2O.

Chemical physics

Matthew C Patterson, Nathan D Keilbart, Lucy W Kiruri, Chad A Thibodeaux, Slawo Lomnicki, Richard L Kurtz, E D Poliakoff, Barry Dellinger, Phillip T Sprunger

Affiliations

  1. Department of Physics and Astronomy, Louisiana State University, Baton Rouge, Louisiana 70803, USA.
  2. Department of Physics and Astronomy, Louisiana State University, Baton Rouge, Louisiana 70803, USA ; Department of Mechanical Engineering, Brigham Young University-Idaho, Rexburg, ID 83460, USA.
  3. Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, USA.

PMID: 24443627 PMCID: PMC3891583 DOI: 10.1016/j.chemphys.2012.12.003

Abstract

We have examined the formation of environmentally persistent free radicals (EPFRs) from phenol over alumina and titania using both powder and single-crystal samples. Electron paramagnetic resonance (EPR) studies of phenol adsorbed on metal oxide powders indicates radical formation on both titania and alumina, with both oxides forming one faster-decaying species (lifetime on the order of 50-100 hours) and one slower-decayng species (lifetimes on the order of 1000 hours or more). Electron energy loss spectroscopy (EELS) measurements comparing physisorbed phenol on single-crystal TiO

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