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Baljak S, Russell AD, Binding SC, et al. Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers. J Am Chem Soc. 2014;136(16):5864-7doi: 10.1021/ja5014745.
Baljak, S., Russell, A. D., Binding, S. C., Haddow, M. F., O'Hare, D., & Manners, I. (2014). Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers. Journal of the American Chemical Society, 136(16), 5864-7. https://doi.org/10.1021/ja5014745
Baljak, Sladjana, et al. "Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers." Journal of the American Chemical Society vol. 136,16 (2014): 5864-7. doi: https://doi.org/10.1021/ja5014745
Baljak S, Russell AD, Binding SC, Haddow MF, O'Hare D, Manners I. Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers. J Am Chem Soc. 2014 Apr 23;136(16):5864-7. doi: 10.1021/ja5014745. Epub 2014 Apr 08. PMID: 24712387.
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J Am Chem Soc. 2014 Apr 23;136(16):5864-7. doi: 10.1021/ja5014745. Epub 2014 Apr 08.

Ring-opening polymerization of a strained [3]nickelocenophane: a route to polynickelocenes, a class of S = 1 metallopolymers.

Journal of the American Chemical Society

Sladjana Baljak, Andrew D Russell, Samantha C Binding, Mairi F Haddow, Dermot O'Hare, Ian Manners

Affiliations

  1. School of Chemistry, University of Bristol , Bristol BS8 1TS, United Kingdom.

PMID: 24712387 DOI: 10.1021/ja5014745

Abstract

We report the synthesis, reactivity studies, and ring-opening polymerization of a tricarba[3]nickelocenophane. The resulting green polynickelocene (5) possesses a -(CH2)3- spacer between the nickelocene units and is shown to be of high molecular weight. SQUID magnetometry measurements indicate that 5 is a macromolecular material with an S = 1 repeat unit.

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