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Geiger HC, Donohoe JS, Geiger DK. 4-Bromo-2-(5-bromo-thio-phen-2-yl)-1-[(5-bromo-thio-phen-2-yl)meth-yl]-5,6-dimethyl-1H-benzimidazole. Acta Crystallogr Sect E Struct Rep Online. 2014;70:o486-7doi: 10.1107/S160053681400628X.
Geiger, H. C., Donohoe, J. S., & Geiger, D. K. (2014). 4-Bromo-2-(5-bromo-thio-phen-2-yl)-1-[(5-bromo-thio-phen-2-yl)meth-yl]-5,6-dimethyl-1H-benzimidazole. Acta crystallographica. Section E, Structure reports online, 70o486-7. https://doi.org/10.1107/S160053681400628X
Geiger, H Cristina, et al. "4-Bromo-2-(5-bromo-thio-phen-2-yl)-1-[(5-bromo-thio-phen-2-yl)meth-yl]-5,6-dimethyl-1H-benzimidazole." Acta crystallographica. Section E, Structure reports online vol. 70 (2014): o486-7. doi: https://doi.org/10.1107/S160053681400628X
Geiger HC, Donohoe JS, Geiger DK. 4-Bromo-2-(5-bromo-thio-phen-2-yl)-1-[(5-bromo-thio-phen-2-yl)meth-yl]-5,6-dimethyl-1H-benzimidazole. Acta Crystallogr Sect E Struct Rep Online. 2014 Mar 26;70:o486-7. doi: 10.1107/S160053681400628X. eCollection 2014 Apr 01. PMID: 24826179; PMCID: PMC3998606.
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Acta Crystallogr Sect E Struct Rep Online. 2014 Mar 26;70:o486-7. doi: 10.1107/S160053681400628X. eCollection 2014 Apr 01.

4-Bromo-2-(5-bromo-thio-phen-2-yl)-1-[(5-bromo-thio-phen-2-yl)meth-yl]-5,6-dimethyl-1H-benzimidazole.

Acta crystallographica. Section E, Structure reports online

H Cristina Geiger, James S Donohoe, David K Geiger

Affiliations

  1. Department of Chemistry, State University of New York-College at Geneseo, 1 College Circle, Geneseo, NY 14454, USA.

PMID: 24826179 PMCID: PMC3998606 DOI: 10.1107/S160053681400628X

Abstract

The title compound, C18H13Br3N2S2, was obtained via the reaction of N-bromo-succinamide with 5,6-dimethyl-2-(thio-phen-2-yl)-1-[(thio-phen-2-yl)meth-yl]-1H-benzimidazole. The compound exhibits rotational disorder of the 5-bromo-thio-phen-2-yl substituent with a refined major:minor occupancy ratio of 0.876 (7):0.124 (7). The 5-bromo-thio-phen-2-yl mean plane is canted to the benzimidazole plane by 20.0 (4) and 21 (4)° in the major and minor components, respectively. In the crystal, weak C-H⋯N inter-actions link the mol-ecules into infinite C(7) chains along the 21 axes.

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