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Boutebdja M, Lehleh A, Beghidja A, et al. A new polymorph of aqua-bis-(1,10-phenanthroline-κ(2) N,N')copper(II) dinitrate. Acta Crystallogr Sect E Struct Rep Online. 2014;70:m185-6doi: 10.1107/S1600536814008198.
Boutebdja, M., Lehleh, A., Beghidja, A., Setifi, Z., & Merazig, H. (2014). A new polymorph of aqua-bis-(1,10-phenanthroline-κ(2) N,N')copper(II) dinitrate. Acta crystallographica. Section E, Structure reports online, 70m185-6. https://doi.org/10.1107/S1600536814008198
Boutebdja, Mehdi, et al. "A new polymorph of aqua-bis-(1,10-phenanthroline-κ(2) N,N')copper(II) dinitrate." Acta crystallographica. Section E, Structure reports online vol. 70 (2014): m185-6. doi: https://doi.org/10.1107/S1600536814008198
Boutebdja M, Lehleh A, Beghidja A, Setifi Z, Merazig H. A new polymorph of aqua-bis-(1,10-phenanthroline-κ(2) N,N')copper(II) dinitrate. Acta Crystallogr Sect E Struct Rep Online. 2014 Apr 18;70:m185-6. doi: 10.1107/S1600536814008198. eCollection 2014 May 01. PMID: 24860316; PMCID: PMC4011280.
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Acta Crystallogr Sect E Struct Rep Online. 2014 Apr 18;70:m185-6. doi: 10.1107/S1600536814008198. eCollection 2014 May 01.

A new polymorph of aqua-bis-(1,10-phenanthroline-κ(2) N,N')copper(II) dinitrate.

Acta crystallographica. Section E, Structure reports online

Mehdi Boutebdja, Asma Lehleh, Adel Beghidja, Zouaoui Setifi, Hocine Merazig

Affiliations

  1. Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine, Algeria.

PMID: 24860316 PMCID: PMC4011280 DOI: 10.1107/S1600536814008198

Abstract

The title mol-ecule, [Cu(C12H8N2)2(H2O)](NO3)2, is a new polymorph of a compound which up to now has been reported to crystallize space groups in C2/c and Cc. The crystal studied was twinned by non-merohedry (final BASF factor of 0.40043) with the structure being solved and refined in P-1. The Cu(II) atom is coordinated by four N atoms from two 1,10-phenanthroline ligands and an O atom from a water mol-ecule in an approximate trigonal-bipyramidal geometry. Discrete entities of one cation and two nitrate anions are formed by water-nitrate O-H⋯O hydrogen bonds. The components are further assembled into a three-dimensional network by C-H⋯O hydrogen bonds.

References

  1. Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22 - PubMed
  2. Chemistry. 2010 Feb 1;16(5):1691-6 - PubMed

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