Display options
Cite
Al-Masum M, Saleh N, Islam T. A novel route to organonitrites by Pd-catalyzed cross-coupling of sodium nitrite and potassium organotrifluoroborates. Tetrahedron Lett. 2013;54(9):1141-1144doi: 10.1016/j.tetlet.2012.12.047.
Al-Masum, M., Saleh, N., & Islam, T. (2013). A novel route to organonitrites by Pd-catalyzed cross-coupling of sodium nitrite and potassium organotrifluoroborates. Tetrahedron letters, 54(9), 1141-1144. https://doi.org/10.1016/j.tetlet.2012.12.047
Al-Masum, Mohammad, et al. "A novel route to organonitrites by Pd-catalyzed cross-coupling of sodium nitrite and potassium organotrifluoroborates." Tetrahedron letters vol. 54,9 (2013): 1141-1144. doi: https://doi.org/10.1016/j.tetlet.2012.12.047
Al-Masum M, Saleh N, Islam T. A novel route to organonitrites by Pd-catalyzed cross-coupling of sodium nitrite and potassium organotrifluoroborates. Tetrahedron Lett. 2013 Feb 01;54(9):1141-1144. doi: 10.1016/j.tetlet.2012.12.047. PMID: 24926109; PMCID: PMC4051233.
Copy Download .nbib Format: NLM
Share it on

Tetrahedron Lett. 2013 Feb 01;54(9):1141-1144. doi: 10.1016/j.tetlet.2012.12.047.

A novel route to organonitrites by Pd-catalyzed cross-coupling of sodium nitrite and potassium organotrifluoroborates.

Tetrahedron letters

Mohammad Al-Masum, Nabil Saleh, Tasfia Islam

Affiliations

  1. Department of Chemistry, Tennessee State University, 3500 John A. Merritt Blvd., Nashville, TN 37209, United States.

PMID: 24926109 PMCID: PMC4051233 DOI: 10.1016/j.tetlet.2012.12.047

Abstract

Microwave irradiated palladium-catalyzed cross-coupling reaction of potassium styryltrifluoroborates and sodium nitrite gives the corresponding styryl nitrites in high yields. Potassium aryltrifluoroborates also furnish aryl nitrites under same reaction condition. This unprecedented cross-coupling is an interesting development and has the potential to lead to new nitration protocols.

Keywords: Microwave; Organonitrites; Organotrifluoroborates; Sodium nitrite in cross-coupling

References

  1. Org Lett. 2006 May 11;8(10):2031-4 - PubMed
  2. Org Lett. 2006 Jan 5;8(1):11-3 - PubMed
  3. Chem Rev. 1996 Dec 19;96(8):3241-3268 - PubMed
  4. J Am Chem Soc. 2009 Sep 16;131(36):12898-9 - PubMed
  5. J Am Chem Soc. 2006 Jun 28;128(25):8150-1 - PubMed
  6. Acc Chem Res. 2007 Apr;40(4):275-86 - PubMed
  7. Chem Rev. 2008 Jan;108(1):288-325 - PubMed

Publication Types

Grant support