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Hurkes N, Ehmann HM, List M, et al. Silanol-based surfactants: synthetic access and properties of an innovative class of environmentally benign detergents. Chemistry. 2014;20(30):9330-5doi: 10.1002/chem.201402857.
Hurkes, N., Ehmann, H. M., List, M., Spirk, S., Bussiek, M., Belaj, F., & Pietschnig, R. (2014). Silanol-based surfactants: synthetic access and properties of an innovative class of environmentally benign detergents. Chemistry (Weinheim an der Bergstrasse, Germany), 20(30), 9330-5. https://doi.org/10.1002/chem.201402857
Hurkes, Natascha, et al. "Silanol-based surfactants: synthetic access and properties of an innovative class of environmentally benign detergents." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 20,30 (2014): 9330-5. doi: https://doi.org/10.1002/chem.201402857
Hurkes N, Ehmann HM, List M, Spirk S, Bussiek M, Belaj F, Pietschnig R. Silanol-based surfactants: synthetic access and properties of an innovative class of environmentally benign detergents. Chemistry. 2014 Jul 21;20(30):9330-5. doi: 10.1002/chem.201402857. Epub 2014 Jul 01. PMID: 24986309.
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Chemistry. 2014 Jul 21;20(30):9330-5. doi: 10.1002/chem.201402857. Epub 2014 Jul 01.

Silanol-based surfactants: synthetic access and properties of an innovative class of environmentally benign detergents.

Chemistry (Weinheim an der Bergstrasse, Germany)

Natascha Hurkes, Heike M A Ehmann, Martina List, Stefan Spirk, Malte Bussiek, Ferdinand Belaj, Rudolf Pietschnig

Affiliations

  1. Universität Kassel, Institut für Chemie and CINSaT, Heinrich-Plett-Strasse 40, 34132 Kassel (Germany), Fax: (+49)?561-804-4649.

PMID: 24986309 DOI: 10.1002/chem.201402857

Abstract

Herein, environmentally friendly surfactants based on new silanols as substitutes for the isoelectronic phosphonates were explored. Surface tensions of aqueous solutions are significantly reduced, particularly with those silanols that feature a high ratio of organic moiety to silanol. Besides their use as surfactants, their potential as coating agents for hydrophilic oxide surfaces was investigated for the example of glass substrates. In the solid-state sheet structures with silanol, double layers are present, in which the sheet spacing varies with the alkyl-chain length.

© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords: main-group elements; metalation; silanes; supramolecular chemistry; sustainable chemistry

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