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Nano Lett. 2014 Jun 11;14(6):3661-7. doi: 10.1021/nl501441w. Epub 2014 May 23.

Atomic resolution monitoring of cation exchange in CdSe-PbSe heteronanocrystals during epitaxial solid-solid-vapor growth.

Nano letters

Anil O Yalcin, Zhaochuan Fan, Bart Goris, Wun-Fan Li, Rik S Koster, Chang-Ming Fang, Alfons van Blaaderen, Marianna Casavola, Frans D Tichelaar, Sara Bals, Gustaaf Van Tendeloo, Thijs J H Vlugt, Daniƫl Vanmaekelbergh, Henny W Zandbergen, Marijn A van Huis

Affiliations

  1. Kavli Institute of Nanoscience, Delft University of Technology , Lorentzweg 1, 2628 CJ Delft, The Netherlands.

PMID: 24844280 PMCID: PMC4055051 DOI: 10.1021/nl501441w

Abstract

Here, we show a novel solid-solid-vapor (SSV) growth mechanism whereby epitaxial growth of heterogeneous semiconductor nanowires takes place by evaporation-induced cation exchange. During heating of PbSe-CdSe nanodumbbells inside a transmission electron microscope (TEM), we observed that PbSe nanocrystals grew epitaxially at the expense of CdSe nanodomains driven by evaporation of Cd. Analysis of atomic-resolution TEM observations and detailed atomistic simulations reveals that the growth process is mediated by vacancies.

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