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RSC Adv. 2014 Jan 01;4(55):28928-28936. doi: 10.1039/C4RA02176B.

Tuning Surface Microstructure and Gradient Property of Polymer by Photopolymerizable Polysiloxane-modified Nanogels.

RSC advances

Cong Chen, JianCheng Liu, Fang Sun, Jeffrey W Stansbury

Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, PR China ; College of Science, Beijing University of Chemical Technology, Beijing 100029, PR China.
  2. Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States.
  3. Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States ; Department of Craniofacial Biology, University of Colorado, Aurora, Colorado 80045, United States.

PMID: 25045518 PMCID: PMC4097311 DOI: 10.1039/C4RA02176B

Abstract

This paper reports a series of photopolymerizable polysiloxane-modified nanogels for regulating surface microstructure and gradient property of polymers, which were synthesized by solution polymerization under different feed ratios of a methacrylate-modified polysiloxane, urethane dimethacrylate (UDMA) and isobornyl methacrylate (IBMA) in the presence of a thiol chain transfer agent. The nanogel structure and composition were characterized by proton nuclear magnetic resonance (

References

  1. Langmuir. 2008 Mar 18;24(6):2294-317 - PubMed
  2. Chem Commun (Camb). 2011 Nov 14;47(42):11754-6 - PubMed
  3. J Biomed Mater Res B Appl Biomater. 2004 Oct 15;71(1):206-13 - PubMed
  4. Biomacromolecules. 2009 May 11;10(5):1282-6 - PubMed
  5. Langmuir. 2013 Mar 26;29(12):4128-39 - PubMed
  6. Langmuir. 2012 Jan 17;28(2):1539-44 - PubMed
  7. J Dent Res. 2011 Apr;90(4):402-16 - PubMed
  8. Dent Mater. 2011 Jun;27(6):509-19 - PubMed
  9. Angew Chem Int Ed Engl. 2009;48(30):5418-29 - PubMed
  10. Eur Polym J. 2012 Nov;48(11):1819-1828 - PubMed

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