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Stark M, Ditze S, Lepper M, et al. Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111). Chem Commun (Camb). 2014;50(71):10225-8doi: 10.1039/c4cc03708a.
Stark, M., Ditze, S., Lepper, M., Zhang, L., Schlott, H., Buchner, F., Röckert, M., Chen, M., Lytken, O., Steinrück, H. P., & Marbach, H. (2014). Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111). Chemical communications (Cambridge, England), 50(71), 10225-8. https://doi.org/10.1039/c4cc03708a
Stark, M, et al. "Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111)." Chemical communications (Cambridge, England) vol. 50,71 (2014): 10225-8. doi: https://doi.org/10.1039/c4cc03708a
Stark M, Ditze S, Lepper M, Zhang L, Schlott H, Buchner F, Röckert M, Chen M, Lytken O, Steinrück HP, Marbach H. Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111). Chem Commun (Camb). 2014 Sep 14;50(71):10225-8. doi: 10.1039/c4cc03708a. PMID: 25052700.
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Chem Commun (Camb). 2014 Sep 14;50(71):10225-8. doi: 10.1039/c4cc03708a.

Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111).

Chemical communications (Cambridge, England)

M Stark, S Ditze, M Lepper, L Zhang, H Schlott, F Buchner, M Röckert, M Chen, O Lytken, H-P Steinrück, H Marbach

Affiliations

  1. Lehrstuhl für Physikalische Chemie II, Egerlandstrasse 3 and Interdisciplinary Center for Molecular Materials (ICMM), Universität Erlangen-Nürnberg, D-91058 Erlangen, Germany. [email protected].

PMID: 25052700 DOI: 10.1039/c4cc03708a

Abstract

Based on a combined scanning tunnelling microscopy and X-ray photoelectron spectroscopy study we present detailed insights into pronounced changes of long-range order and intramolecular conformation during the self-metalation of 2H-5,10,15,20-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin (2HTTBPP) to CuTTBPP on Cu(111). Upon metalation, the porphyrin literally "pops up" from the surface, due to a drastically reduced molecule-substrate interaction.

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