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Chem Commun (Camb). 2014 Oct 07;50(77):11374-7. doi: 10.1039/c4cc04503c.

Metal-free sp(3) C-H functionalization: a novel approach for the syntheses of selenide ethers and thioesters from methyl arenes.

Chemical communications (Cambridge, England)

Satpal Singh Badsara, Yi-Chen Liu, Ping-An Hsieh, Jing-Wen Zeng, Shao-Yi Lu, Yi-Wei Liu, Chin-Fa Lee

Affiliations

  1. Department of Chemistry, National Chung Hsing University, Taichung, Taiwan 402, Republic of China. [email protected].

PMID: 25122526 DOI: 10.1039/c4cc04503c

Abstract

A DTBP-promoted metal-free and solvent-free formation of C-Se and C-S bonds through sp(3) C-H functionalization of methyl arenes with diselenides and disulfides is described.

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