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Fitzmaurice D, Rao SN, Preece JA, et al. Heterosupramolecular chemistry: programmed pseudorotaxane assembly at the surface of a nanocrystal. Angew Chem Int Ed Engl. 1999;38(8):1147-50doi: 10.1002/(SICI)1521-3773(19990419)38:8<1147::AID-ANIE1147>3.0.CO;2-A.
Fitzmaurice, D., Rao, S. N., Preece, J. A., Stoddart, J. F., Wenger, S., & Zaccheroni, N. (1999). Heterosupramolecular chemistry: programmed pseudorotaxane assembly at the surface of a nanocrystal. Angewandte Chemie (International ed. in English), 38(8), 1147-50. https://doi.org/10.1002/(SICI)1521-3773(19990419)38:8<1147::AID-ANIE1147>3.0.CO;2-A
Fitzmaurice, D, et al. "Heterosupramolecular chemistry: programmed pseudorotaxane assembly at the surface of a nanocrystal." Angewandte Chemie (International ed. in English) vol. 38,8 (1999): 1147-50. doi: https://doi.org/10.1002/(SICI)1521-3773(19990419)38:8<1147::AID-ANIE1147>3.0.CO;2-A
Fitzmaurice D, Rao SN, Preece JA, Stoddart JF, Wenger S, Zaccheroni N. Heterosupramolecular chemistry: programmed pseudorotaxane assembly at the surface of a nanocrystal. Angew Chem Int Ed Engl. 1999;38(8):1147-50. doi: 10.1002/(SICI)1521-3773(19990419)38:8<1147::AID-ANIE1147>3.0.CO;2-A. PMID: 25138525.
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Angew Chem Int Ed Engl. 1999;38(8):1147-50. doi: 10.1002/(SICI)1521-3773(19990419)38:8<1147::AID-ANIE1147>3.0.CO;2-A.

Heterosupramolecular chemistry: programmed pseudorotaxane assembly at the surface of a nanocrystal.

Angewandte Chemie (International ed. in English)

D Fitzmaurice, S N Rao, J A Preece, J F Stoddart, S Wenger, N Zaccheroni

Affiliations

  1. Department of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland, Fax: (+353)?1-706-2441. [email protected].

PMID: 25138525 DOI: 10.1002/(SICI)1521-3773(19990419)38:8<1147::AID-ANIE1147>3.0.CO;2-A

Abstract

Gold nanocrystals, stabilized by thiols covalently bound to a dibenzo[24]crown-8 moiety, have been programmed to recognize and selectively bind dibenzylammonium cations in solution. This results in a self-organization process at the surface of a nanocrystal with the assembly of a pseudorotaxane (see picture).

Copyright © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Keywords: Crown compounds; Nanostructures; Pseudorotaxanes; Self-organization

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