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Bhattacharyya S, Chakraborty A, Jayaramulu K, et al. A bimodal anionic MOF: turn-off sensing of Cu(II) and specific sensitization of Eu(III.). Chem Commun (Camb). 2014;50(88):13567-70doi: 10.1039/c4cc05991c.
Bhattacharyya, S., Chakraborty, A., Jayaramulu, K., Hazra, A., & Maji, T. K. (2014). A bimodal anionic MOF: turn-off sensing of Cu(II) and specific sensitization of Eu(III.). Chemical communications (Cambridge, England), 50(88), 13567-70. https://doi.org/10.1039/c4cc05991c
Bhattacharyya, Sohini, et al. "A bimodal anionic MOF: turn-off sensing of Cu(II) and specific sensitization of Eu(III.)." Chemical communications (Cambridge, England) vol. 50,88 (2014): 13567-70. doi: https://doi.org/10.1039/c4cc05991c
Bhattacharyya S, Chakraborty A, Jayaramulu K, Hazra A, Maji TK. A bimodal anionic MOF: turn-off sensing of Cu(II) and specific sensitization of Eu(III.). Chem Commun (Camb). 2014 Nov 14;50(88):13567-70. doi: 10.1039/c4cc05991c. PMID: 25243506.
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Chem Commun (Camb). 2014 Nov 14;50(88):13567-70. doi: 10.1039/c4cc05991c.

A bimodal anionic MOF: turn-off sensing of Cu(II) and specific sensitization of Eu(III.).

Chemical communications (Cambridge, England)

Sohini Bhattacharyya, Anindita Chakraborty, Kolleboyina Jayaramulu, Arpan Hazra, Tapas Kumar Maji

Affiliations

  1. Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India. [email protected].

PMID: 25243506 DOI: 10.1039/c4cc05991c

Abstract

A novel porous anionic MOF {[Mg3(ndc)2.5(HCO2)2(H2O)][NH2Me2]·2H2O·DMF} (1) having exchangeable dimethyl amine cations in 1D channels has been synthesized and characterized. Through cation exchange, 1 manifests bimodal functionality, being a turn-off sensor of Cu(II) on one hand, and a selective sensitizer of Eu(III) emitting intense pure red emission on the other.

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