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Alexe-Ionescu AL, Barbero G, Lelidis I. Independence of the effective dielectric constant of an electrolytic solution on the ionic distribution in the linear Poisson-Nernst-Planck model. J Chem Phys. 2014;141(8):084505doi: 10.1063/1.4893712.
Alexe-Ionescu, A. L., Barbero, G., & Lelidis, I. (2014). Independence of the effective dielectric constant of an electrolytic solution on the ionic distribution in the linear Poisson-Nernst-Planck model. The Journal of chemical physics, 141(8), 084505. https://doi.org/10.1063/1.4893712
Alexe-Ionescu, A L, et al. "Independence of the effective dielectric constant of an electrolytic solution on the ionic distribution in the linear Poisson-Nernst-Planck model." The Journal of chemical physics vol. 141,8 (2014): 084505. doi: https://doi.org/10.1063/1.4893712
Alexe-Ionescu AL, Barbero G, Lelidis I. Independence of the effective dielectric constant of an electrolytic solution on the ionic distribution in the linear Poisson-Nernst-Planck model. J Chem Phys. 2014 Aug 28;141(8):084505. doi: 10.1063/1.4893712. PMID: 25173019.
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J Chem Phys. 2014 Aug 28;141(8):084505. doi: 10.1063/1.4893712.

Independence of the effective dielectric constant of an electrolytic solution on the ionic distribution in the linear Poisson-Nernst-Planck model.

The Journal of chemical physics

A L Alexe-Ionescu, G Barbero, I Lelidis

Affiliations

  1. Faculty of Applied Sciences, University Politehnica of Bucharest, Splaiul Independentei 313, 060042 Bucharest, Romania.
  2. Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy.
  3. Solid State Section, Department of Physics, University of Athens, Panepistimiopolis, Zografos, Athens 157 84, Greece.

PMID: 25173019 DOI: 10.1063/1.4893712

Abstract

We consider the influence of the spatial dependence of the ions distribution on the effective dielectric constant of an electrolytic solution. We show that in the linear version of the Poisson-Nernst-Planck model, the effective dielectric constant of the solution has to be considered independent of any ionic distribution induced by the external field. This result follows from the fact that, in the linear approximation of the Poisson-Nernst-Planck model, the redistribution of the ions in the solvent due to the external field gives rise to a variation of the dielectric constant that is of the first order in the effective potential, and therefore it has to be neglected in the Poisson's equation that relates the actual electric potential across the electrolytic cell to the bulk density of ions. The analysis is performed in the case where the electrodes are perfectly blocking and the adsorption at the electrodes is negligible, and in the absence of any ion dissociation-recombination effect.

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